“…6 and listed in Table 5 are, however, still reliant upon some form of sample manipulation for the required selectivity, that adds considerably to cost. Furthermore, the detection of gas samples is quite problematic, especially at low concentrations [153,155,178]: the evolved gas is extremely reactive and will readily adsorb onto surfaces; while this is a feature that is actively exploited in a number of analytical protocols [132,140,[155][156][157][158]167,[171][172][173][174][175][176], it can be the source of erroneous results and poor recoveries, particularly when dealing with field assessments [178][179][180]. Elimination of such problems is a non-trivial task and requires careful handling by trained personnel and the utilization of 'deactivated' surfaces where appropriate.…”