A new preparation of trifluoromethanesulfinate salts

Mn-Mediated Electrochemical Trifluoromethylation/C(sp2)–H Functionalization Cascade for the Synthesis of Azaheterocycles

“…In accord with literature, free CF 3 SO 2 Na reagent shows a singlet peak at −87.5 ppm. 14 When electric current of 1.1 F/mol was applied, the 19 F NMR signal of CF 3 SO 2 Na disappeared, indicating its complete consumption upon electrolysis. New peaks around −73.0 ppm appearance indicated new CF 3 species formation (Figure S4).…”

Dioxygen mediated hydroacylation of vinyl sulfonates and sulfones on water

“…23 Thus, treatment of sulfonates 3a, 3ab and 3ac with DBU and a thiol in dichloromethane led to a smooth and high yielding transformation to 11, presumably via an elimination-addition sequence (Table 4, entries 1-6). As the elimination of sulfones to give alkenes is well documented, 24 the elimination conditions were applied to sulfones 3ad and 3ae (Table 4, entries 7-10) and were successful, albeit in poorer yields. We believe the inferior yields observed for b-keto-sulfones 3ad and 3ae highlight a specific advantage of b-keto-sulfonates 3a, 3ab and 3ac.…”

Synthesis and applications of sodium sulfinates (RSO2Na): a powerful building block for the synthesis of organosulfur compounds

“…Concurrently, Langlois and co-workers developed sustainable and mild reaction conditions to synthesize trifluoromethane-sulfinate (triflinate) salts via β-elimination of aliphatic triflones using NaOMe in MeOH ( Scheme 12C ). 45 As a result, this reagent is well known as the Langlois reagent.…”