2022
DOI: 10.1016/j.solidstatesciences.2022.106831
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A new salt-inclusion compound, |Ag4Br|@[B7O12], with a novel type of the porous double-layered borate anion and strong anharmonicity of the “guest” sublattice

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Cited by 8 publications
(6 citation statements)
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“…13–23 Among hilgardites, iodides exhibit the greatest NLO efficiency, 24 which prompted us to look for M 3 B 6 O 10 I. Besides Na + and K + , Ag + is also a promising candidate as shown by the successful synthesis of Ag 4 B 4 O 7 X 2 (X = Br and I) 25 and Ag 4 B 7 O 12 Br, 26 which have complex architectures (Fig. S1†).…”
mentioning
confidence: 99%
“…13–23 Among hilgardites, iodides exhibit the greatest NLO efficiency, 24 which prompted us to look for M 3 B 6 O 10 I. Besides Na + and K + , Ag + is also a promising candidate as shown by the successful synthesis of Ag 4 B 4 O 7 X 2 (X = Br and I) 25 and Ag 4 B 7 O 12 Br, 26 which have complex architectures (Fig. S1†).…”
mentioning
confidence: 99%
“…Recently, salt-inclusion silver halide borates have attracted much attention and several crystals have been obtained, for example, Ag 4 B 4 O 7 X 2 (X = Br, I) with strongly anisotropic thermal expansion, [16a] two noncentrosymmetric silver borate halides j Ag 4 X 2 j @[B 4 O 7 ] (X = Br, I) and Ag 3 B 6 O 10 I being a promising solid-state electrolyte. [19] These works are mainly dedicated to the synthesis and characterization of new silver borates. Being an important branch of borates, silver borates may play a great role in these fields with further development.…”
Section: Introductionmentioning
confidence: 99%
“…9 Because silver cations are prone to reduction, conferring low stability to the corresponding borates, their chemistry is less studied compared to the alkali cations. Recently, we succeeded in partially overcoming this obstacle and prepared a number of new silver borate halides, including Ag 4 B 4 O 7 X 2 , where X = Br and I, 10 Ag 3 B 6 O 10 I, 11 and Ag 4 B 7 O 12 Br, 12 yet earlier attempts to prepare the corresponding chlorides had not been successful. The compounds noted above adopt salt-inclusion structures containing two sublattices (silver halide and boron oxide).…”
mentioning
confidence: 99%
“…Crystal structures of Ag 4 B 7 O 12 X, where X = (a) Cl, (b) Br, and (c) I, viewed along b and the corresponding thermal expansion tensors. On the right panels are the corresponding silver halide sublattices; the short Ag···Ag of 2.5–2.6 Å are shown as dotted lines.…”
mentioning
confidence: 99%
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