2010
DOI: 10.1002/cjoc.201090328
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A New Sensor for Simultaneous Determination of Tyrosine and Dopamine Using Iron(III) Doped Zeolite Modified Carbon Paste Electrode

Abstract: A new chemically modified electrode is constructed based on iron(III) doped zeolite modified carbon paste electrode (Fe 3+ Y/ZMCPE). The new sensor could be used for the simultaneous determination of the biologically important compounds dopamine (DA) and tyrosine (Tyr). The measurements are carried out using differential pulse voltammetric (

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Cited by 32 publications
(8 citation statements)
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“…The limit of detection (LOD) and limit of quantification (LOQ) for TY were calculated by using the following formulas, LOD=3 S/M and LOQ=10 S/M (where S is the standard deviation of blank and M is the slope of the calibration plot), obtained values of LOD and LOQ were 729 nM and 2.43 µM respectively. The obtained detection limit was compared with some related works were reported in Table 1 5,10,29-32 and confirms that SDS/CNTPE has nearly comparable sensitivity and nearer limit of detection.…”
Section: Resultssupporting
confidence: 76%
“…The limit of detection (LOD) and limit of quantification (LOQ) for TY were calculated by using the following formulas, LOD=3 S/M and LOQ=10 S/M (where S is the standard deviation of blank and M is the slope of the calibration plot), obtained values of LOD and LOQ were 729 nM and 2.43 µM respectively. The obtained detection limit was compared with some related works were reported in Table 1 5,10,29-32 and confirms that SDS/CNTPE has nearly comparable sensitivity and nearer limit of detection.…”
Section: Resultssupporting
confidence: 76%
“…In this method, the electrode was designed with different concentrations of thrombin (5,10,20,25,50, 100, 200 and 500 pg. mL −1 ) and their ECL intensities were measured.…”
Section: Ratiometric Methodmentioning
confidence: 99%
“…Since the ECL responses of the CdS and luminol are dependent on the H 2 O 2 concentration in PBS, we carried out the experiments to evaluate and obtain the optimal H 2 O 2 concentration. To do this, in QM and AM, the electrode was prepared using 1000 pg.mL −1 thrombin and used as the working electrode in a PBS (0.1 M, pH = 7.5) with different concentrations of H 2 O 2 (5,10,15,20,25,30,35,40 and 50 mM) at 0.1 V. s −1 . The resulted ECL intensities and peaks are presented in Supplementary material, Fig.…”
Section: H 2 O 2 Concentration Optimizationmentioning
confidence: 99%
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“…[2][3][4][5][6][7] Diffusion coefficient "D, cm 2 s -1 " values were calculated from Randles-Sevcik equation for a quasi-reversible process. [45][46][47][48] For the electro-oxidation process of L-dopa where n = 2, C =1×10 -6 mol/cm 3 , and the geometrical surface area of CPE (A) = 0.312 cm 2 ; the calculated D values of L-dopa at CPE, CILCE, Au/CPE and Au/CILCE were 4.19×10 -6 cm 2 s -1 , 5.53×10 -6 cm 2 s -1 , 6.18×10 -6 cm 2 s -1 and 2.47×10 -5 cm 2 s -1 , respectively displaying the highest value at Au/CILCE. This suggests that there is enhancing in the mass transfer process of L-dopa from solution bulk to electrode surface and/or the charge transfer process during the electro-oxidation of L-dopa at electrode surface.…”
Section: Influence Of Scan Rate On the Electro-oxidation Of L-dopamentioning
confidence: 99%