In general, ordered algebraic structures, particularly ordered semigroups, play an important role in fuzzification in many applied areas, such as computer science, formal languages, coding theory, error correction, etc. Nowadays, the concept of ambiguity is important in dealing with a variety of issues related to engineering modeling problems, network theory, decision-making problems in real-life situations, and so on. Several theories have been developed by various researchers to overcome the difficulties that arise from uncertainty, including fuzzy sets, intuitionistic fuzzy sets, probability, soft sets, neutrosophic sets, and many more. In this paper, we focus solely on neutrosophic set theory. In ordered semigroups, we define and investigate the properties of neutrosophic κ-ideals and neutrosophic κ-interior ideals. We also use neutrosophic κ-ideals and neutrosophic κ-interior ideals to characterize ordered semigroups.