A new synthetic pathway for tris-μ-disulfido-μ3-thio-triangulo-trimolybdenum(IV) complexes: preparation, characterization and structure of [Mo3S(S2)3(OOCCHSCH2COOH)3]2−

Preparation and characterization of molybdenum sulfide supported on β-zeolites obtained from [Mo3S4(H2O)9]4+ precursor

“…procedure derived from that of Hegetschweiler et al[11]; third, the synthesis of[Mo 3 S 4 (H 2 O) 9 ] 4+ from [Mo 3 S 7 Cl 6 ] 2À by sulfur elimination using stoichiometric quantities of triphenylphosphine in CH 3 CN [12]. 2.1.2.1.…”

Collision‐Induced Decomposition (CID) of Triangular [Mo3S7‐xSex]4+ Complexes (x = 0,3,7). A liquid SIMS and FTMS/MS study of [Mo3S7‐xSex(Et2NCS2)3] +

“…The two atoms of these bridging groups are inequivalent and occupy an equatorial (in plane) and an axial (out of plane) position with respect to the Mo, triangle. Some characteristic reactivities of these cores have been established in solution: i ) substitution of the peripheral ligands under complete preservation of the Mo,X, core [1][2][3][4][5] [8] [9]; ii) elimination of the three atoms in equatorial position by suitable nucleophilic agents, resulting in complexes containing the [Mo3X4I4+ core [I] [9] [ll-141; iii) anion binding by the three atoms in axial position [4] [5] [8-lo]. However, no mechanistic details about these reactions are known so far.…”

Direct Synthesis and Mass Spectroscopic Observation of the {M40} Polyoxothiometalate Wheel

“…[14] The first step for the preparation of these compounds usually involves a direct sulfurisation process to provide thioanions which are precursors for more sophisticated species by means of reactions with electrophiles (H + or Cu 2+ ) [15] or nucleophiles (cyanido or trialkylphosphane). [16][17][18] The last decade though has given a plethora of unprecedented architectures with interesting properties [19] expanding the limited family of POTM-based compounds because of the fruitful efforts of Sécheresse, Cadot, Dolbecq et al…”