Spectral data offer a means of estimating the critical parameters of sediments, including sediment composition, moisture content, surface roughness, density, and grain-size distribution. Macroscopic surface roughness in particular has a substantial impact on the structure of the bidirectional reflectance factor (BRF) and the angular distribution of scattered light. In developing the models to invert the properties of the surface beyond just surface composition, roughness must also be accounted for in order to achieve reliable and repeatable results. This paper outlines laboratory studies in which the BRF and surface digital elevation measurements were performed on dry clay sediments. The results were used to explore the suitability of various roughness metrics to account for the radiometric effect of surface roughness. The metrics that are specifically addressed in this paper include random roughness and sill variance. Relative accuracy and tradeoffs between these metrics are described. We find that spectral variability, especially near spectral absorption features, correlates strongly with the quantified measures of surface roughness. We also find that spectral variability is sensitive to the sensor fore-optic size. The results suggest that roughness parameters might be directly determined from the spectrum itself. The relationship between spectral variability and macroscopic surface roughness was particularly strong in some broad spectral ranges of the visible, near infrared, and shortwave infrared, including the near-infrared region between 600 and 850 nm.