“…Among various alternatives, transition-metal complexes (TMCs) and organometallic compounds (OMCs) have been among the most extensively used active materials recently in RRAM devices. [15][16][17] Electrochemically active coordination complexes have lately attracted substantial research interest for memory device applications, as transition metal complexes are solution-processable and robust molecular materials. 18 In metal complexes, interactions among metal ions and ligands facilitate the physicochemical properties to be simply altered by changing the metal and valence state along with the molecular structure of ligands, therefore aiding the development of multilevel electronic states for memory devices.…”
In this paper, we report the synthesis and characterization of mononuclear zinc complex (1) containing redox-active bis(4-antipyrinyl) derivative of 3-cyanoformazanate ligand. Complex (1) was readily obtained by refluxing zinc acetate...
“…Among various alternatives, transition-metal complexes (TMCs) and organometallic compounds (OMCs) have been among the most extensively used active materials recently in RRAM devices. [15][16][17] Electrochemically active coordination complexes have lately attracted substantial research interest for memory device applications, as transition metal complexes are solution-processable and robust molecular materials. 18 In metal complexes, interactions among metal ions and ligands facilitate the physicochemical properties to be simply altered by changing the metal and valence state along with the molecular structure of ligands, therefore aiding the development of multilevel electronic states for memory devices.…”
In this paper, we report the synthesis and characterization of mononuclear zinc complex (1) containing redox-active bis(4-antipyrinyl) derivative of 3-cyanoformazanate ligand. Complex (1) was readily obtained by refluxing zinc acetate...
“…7,8 Sn-C bond cleavage has also been observed in some instances. 9 Their potential utility in the field of catalysis, 10 optoelectronics, 11 resistive switching devices, [12][13][14] and biologically driven areas 15,16 has given further impetus in this area.…”
We report the isolation of five new discrete diorganotin di-/mono-carboxylates structures achieved by employing an intramolecular coordination approach. Two diorganotin dicarboxylates, complex 1 and 2, were obtained from reactions of...
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