We consider here chiral symmetry breaking in quantum chromodynamics arising from gluon condensates in vacuum. Through coherent states of gluons simulating a mean field type of approximation, we show that the off-shell gluon condensates of vacuum generate a mass-like contribution for the quarks, giving rise to chiral symmetry breaking. We next note that spontaneous breaking of global chiral symmetry links the four component quark field operator to the pion wave function. This in turn yields many hadronic properties in the light quark sector in agreement with experiments, leading to the conclusion that low energy hadron properties are primarily driven by the vacuum structure of quantum chromodynamics.