In the paper, a family of bivariate super spline spaces of arbitrary degree defined on a triangulation with Powell-Sabin refinement is introduced. It includes known spaces of arbitrary smoothness r and degree 3r − 1 but provides also other choices of spline degree for the same r which, in particular, generalize a known space of C 1 cubic super splines. Minimal determining sets of the proposed super spline spaces of arbitrary degree are presented, and the interpolation problems that uniquely specify their elements are provided. Furthermore, a normalized representation of the discussed splines is considered. It is based on the definition of basis functions that have local supports, are nonnegative, and form a partition of unity. The basis functions share numerous similarities with classical univariate B-splines.