Let A be the path algebra of a Dynkin quiver over a finite field, and let C 1 (P) be the category of 1-cyclic complexes of projective A-modules. In the present paper, we give a PBW-basis and a minimal set of generators for the Hall algebra H (C 1 (P)) of C 1 (P). Using this PBW-basis, we firstly prove the degenerate Hall algebra of C 1 (P) is the universal enveloping algebra of the Lie algebra spanned by all indecomposable objects. Secondly, we calculate the relations in the generators in H (C 1 (P)), and obtain quantum Serre relations in a quotient of certain twisted version of H (C 1 (P)). Moreover, we establish relations between the degenerate Hall algebra, twisted Hall algebra of A and those of C 1 (P), respectively.2010 Mathematics Subject Classification. 16G20, 17B20, 17B37.