A novel 3D coordination polymer [Cd15(μ4-Mtta)12(μ3-Mtta)6(μ3-SO4)4(μ3-OH)4]: Synthesis, structure and solid properties

Ding, You-Bang; Cheng, Ying; Zhang, Zhiling; Zhang, Jing; Yin, Yuan‐Qi; Gao, Wenhua

doi:10.1016/j.inoche.2008.11.001

Inorganic Chemistry Communications

2009

DOI: 10.1016/j.inoche.2008.11.001

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A novel 3D coordination polymer [Cd15(μ4-Mtta)12(μ3-Mtta)6(μ3-SO4)4(μ3-OH)4]: Synthesis, structure and solid properties

You-Bang Ding

Ying Cheng

Zhiling Zhang

et al.

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Cited by 10 publications

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Hydrothermal Synthesis of Two Zinc Coordination Polymers with 1‐(1H‐Tetrazol‐5‐ylmethyl)‐1H‐benzotriazole Ligands

Sun¹,

Jin²,

Shi³

et al. 2013

Zeitschrift anorg allge chemie

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The direct reaction of ZnBr2 with H‐1‐mbtz [1‐mbtz = 1‐(1H‐tetrazol‐5‐ylmethyl)‐1H‐benzotriazole] gives the two‐dimensional complex [Zn(Br)(1‐mbtz)] (1), whereas the reaction of benzotriazol‐1‐yl‐acetonitrile with NaN3 in the presence of water and a Lewis acid (ZnBr2) affords the 2D coordination polymer [Zn2(OH)(1‐mbtz)3H2O] (2). The central zinc atom in 1 is bonded to one terminal bromine atom and three different nitrogen atoms from two tetrazole ligands and one BTA group (BTA = benzotriazole), and each 1‐mbtz ligand is coordinated to three zinc atoms forming a 2D framework. The coordination polyhedron around the metal atom in 2 is a slightly distorted trigonal bipyramid made up by one zinc atom, four nitrogen atoms as well as one oxygen atom, two of the 1‐mbtz ligands coordinated to three zinc atoms and the third 1‐mbtz ligand acts in a bidentate fashion, which leads to the formation of a complicated 2D network. The syntheses and solid‐state structures of the two coordination polymers are reported.

show abstract

Hydrothermal Synthesis of Two Zinc Coordination Polymers with 1‐(1H‐Tetrazol‐5‐ylmethyl)‐1H‐benzotriazole Ligands

Sun¹,

Jin²,

Shi³

et al. 2013

Zeitschrift anorg allge chemie

View full text Add to dashboard Cite

show abstract

Triazoles and tetrazoles: Prime ligands to generate remarkable coordination materials

Aromı́

Barrios

Roubeau

et al. 2011

Coordination Chemistry Reviews

926

471

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Cluster/cage-based coordination polymers with tetrazole derivatives

Kang

Tang

Yang

et al. 2020

Coordination Chemistry Reviews

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A novel 3D coordination polymer [Cd15(μ4-Mtta)12(μ3-Mtta)6(μ3-SO4)4(μ3-OH)4]: Synthesis, structure and solid properties

Cited by 10 publications

References 18 publications

Hydrothermal Synthesis of Two Zinc Coordination Polymers with 1‐(1H‐Tetrazol‐5‐ylmethyl)‐1H‐benzotriazole Ligands

Hydrothermal Synthesis of Two Zinc Coordination Polymers with 1‐(1H‐Tetrazol‐5‐ylmethyl)‐1H‐benzotriazole Ligands

Triazoles and tetrazoles: Prime ligands to generate remarkable coordination materials

Cluster/cage-based coordination polymers with tetrazole derivatives

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