A novel 3D homochiral helical coordination polymer based on a flexible tripodal ligand

A new zinc(II)-based coordination polymer {[Zn(5-fip)(tdbpy)]·(DMF)}n (1) {5-H2fip=5-fluoroisophthalic acid, tdbpy=4,4′-(2,4,8,10-tetraoxaspiro[5.5]undecane-3,9-diyl)bispyridine, DMF=dimethylformamide} has been solvothermally synthesized and structurally characterized. Single-crystal X-ray diffraction revealed that complex 1 shows a unique two-dimensional network architecture containing single-stranded [Zn(5-fip)]n and double-stranded helical [Zn(tdbpy)]n chains. The thermal and luminescence properties of complex 1 have also been studied.

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A novel 3D homochiral helical coordination polymer based on a flexible tripodal ligand

Cited by 3 publications

References 30 publications

A 3D chiral Zn(II) complex based on achiral ligands 2-(1H-imidazolyl-1-methyl)-1H-benzimidazole and adipate

A 3D chiral Zn(II) complex based on achiral ligands 2-(1H-imidazolyl-1-methyl)-1H-benzimidazole and adipate

Two 2D Coordination Polymers Derived by Tripodal Ligand Pyridin-4-ylmethyl-3,5-bis(pyridin-4-ylmethoxy)benzoate

A zinc(II) coordination polymer containing single- and double-stranded helical chains: synthesis, crystal structure, and thermal and luminescence properties

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