“…Polyurethane (PU) adhesives have strong polarity and chemical activity because of their urethane and isocyanate groups, so they can form strong bonding with substrates containing active hydrogen and a variety of pores, such as wood, leather, paper, fabric, ceramics, etc. − Meanwhile, they can also have good chemical adhesion with some substrates with a smooth surface, such as metals, plastics, rubber, glass, etc. , Although traditional solvent-based PU adhesives play an important role in many fields, they cause serious pollution to the environment but also they will increase the full utilization of petroleum resources. − In contrast, waterborne polyurethane (WPU) adhesive is characterized by non-toxicity, environmental protection, as well as safe storage and transportation. WPU adhesive is used in shoe-making, packaging, construction, automobile, medical and health care, aerospace, and a wide range of general bonding. − However, the introduction of hydrophilic groups leads to the deterioration of water resistance, mechanical properties, and thermal stability of the WPU film; as a result, its application in some fields is limited. , …”