2006
DOI: 10.1016/j.jcat.2005.10.021
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A novel approach to synthesizing highly active Ni2P/SiO2 hydrotreating catalysts

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Cited by 165 publications
(92 citation statements)
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“…Lower P/Ni ratio promotes the formation of Ni12P5 phase, which is an intermediate in the formation of Ni2P 25) . In general, the Ni2P phase has higher HDS activity than the Ni12P5 phase 18),21),23), 24) .…”
Section: Nickel Phosphidementioning
confidence: 99%
“…Lower P/Ni ratio promotes the formation of Ni12P5 phase, which is an intermediate in the formation of Ni2P 25) . In general, the Ni2P phase has higher HDS activity than the Ni12P5 phase 18),21),23), 24) .…”
Section: Nickel Phosphidementioning
confidence: 99%
“…[3] A variety of methods for synthesizing bulk metal phosphides, including direct reaction of the appropriate elements for prolonged periods at high temperature, reaction of phosphine with metals or metal oxides, reduction of metal phosphates by hydrogen, electrolysis of molten metal phosphate salts, solid-state metathesis, thermal decomposition of single-source precursors, and self-propagation high-temperature synthesis, are known. [4][5][6] These methods typically require extremely high reaction temperatures (sometimes above 1000 8C) and/or long reaction times. Metal phosphides can be obtained under milder conditions in a solvothermal approach, but this method is not feasible for the deposition of metal phosphides on supports, and in cases where yellow phosphorus and sodium are employed, care must be taken to ensure the rigorous absence of oxygen and water.…”
mentioning
confidence: 99%
“…In contrast, metal phosphides are complicated and difficult to synthesize. Metal phosphide can be prepared by reacting the metal with gaseous PH3 8) , but PH3 is highly toxic and is not readily available commercially. Therefore, solid phosphorous sources, such as phosphate and phosphite, are frequently used for the preparation of supported metal phosphide catalysts.…”
Section: Preparation and Catalytic Performance Of Metal Phosphidesmentioning
confidence: 99%