A Novel Approach to the Synthesis of N-Substituted 1-<i>C</i>-Aminomethyl Glycofuranosides

Vera-Ayoso, Yolanda; Borrachero, Pastora; Cabrera‐Escribano, Francisca; Gómez-Guillén, Manuel; Vogel, Pierre

doi:10.1055/s-2005-922762

Synlett

2006

DOI: 10.1055/s-2005-922762

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A Novel Approach to the Synthesis of N-Substituted 1-C-Aminomethyl Glycofuranosides

Yolanda Vera-Ayoso¹,

Pastora Borrachero²,

Francisca Cabrera‐Escribano³

et al.

Abstract: Reductive amination of formyl C-glycofuranosides, easily available from hexose-derived equatorial-2-OH-glycopyranosides by DAST-promoted ring contraction, afforded N-substituted 1-C-aminomethyl glycofuranosides in most cases in high yields.

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A Novel Approach to the Synthesis of N-Substituted 1-C-Aminomethyl Glycofuranosides

Abstract: Reductive amination of formyl C-glycofuranosides, easily available from hexose-derived equatorial-2-OH-glycopyranosides by DAST-promoted ring contraction, afforded N-substituted 1-C-aminomethyl glycofuranosides in most cases in high yields.

Cited by 0 publications

References 4 publications

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