In response to the era background of “comprehensive electrification” and “dual carbon plan” of electric vehicles, DC/DC converters have a good performance in terms of weight, volume, and efficiency and are widely used in fields such as solar power generation, UPS, communication, computers, and electric vehicles. At present, the DC bus voltage is an important indicator for measuring the safe and stable operation of high-voltage DC power systems in electric vehicles. Therefore, regulating the stability of bus voltage through converters has good economic benefits for the sustainable development of electric vehicles in terms of maintenance costs and effective energy management. In order to solve the problem of bus voltage resonance instability caused by negative impedance characteristics of constant power load in an electric vehicle DC power system, a sliding-mode control design strategy of three-phase interleaved bidirectional converter under constant power load was proposed. Firstly, a GPI observer was designed to estimate the state and concentrated disturbances of the system. Then, the estimated value was introduced into the controller for feedforward compensation, thereby achieving fast-tracking of the output voltage to the reference voltage. Finally, the simulation results show that the controller can effectively maintain the influence of disturbances and better improve tracking characteristics and robustness to disturbances and uncertainties.