2016
DOI: 10.1002/zaac.201600320
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A Novel Copper Oxalate, Na2Cu(C2O4)2

Abstract: A novel copper oxalate Na2Cu(C2O4)2 was synthesised through a hydrothermal method and characterized by single-crystal Xray diffraction. It crystallizes in monoclinic system, P21/n space group with a = 72578 (3)

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Cited by 4 publications
(2 citation statements)
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“…During our previous investigations of metal-oxalate systems, primarily to explore their potential as cathode materials in Li or Na ion batteries, we have observed that several hydrothermally prepared oxalates are characterized by a 2D [Fe­(C 2 O 4 )] ∞ network, with a triangular arrangement of oxalate-bridged magnetic Fe 2+ nodes. Examples include (NH 4 ) 2 Fe­(C 2 O 4 ) 2 ·H 2 O ( A ), K 4 Na 2 [Fe­(C 2 O 4 ) 2 ] 3 ·3H 2 O ( B ), K 2 [Fe­(C 2 O 4 )­(HPO 4 )­(H 2 O)]·H 2 O ( C ), Na 2 Ba 3 [Fe II 3 (C 2 O 4 ) 6 ] [A IV (C 2 O 4 ) 3 ] (A = Sn, Zr) and Na 2 Ba 3 [Fe II 3 (C 2 O 4 ) 6 ]­[A III (C 2 O 4 ) 3 ] 0.5 [A III (C 2 O 4 ) 2 ] 0.5 (A = Al, Fe) ( D ).…”
mentioning
confidence: 99%
“…During our previous investigations of metal-oxalate systems, primarily to explore their potential as cathode materials in Li or Na ion batteries, we have observed that several hydrothermally prepared oxalates are characterized by a 2D [Fe­(C 2 O 4 )] ∞ network, with a triangular arrangement of oxalate-bridged magnetic Fe 2+ nodes. Examples include (NH 4 ) 2 Fe­(C 2 O 4 ) 2 ·H 2 O ( A ), K 4 Na 2 [Fe­(C 2 O 4 ) 2 ] 3 ·3H 2 O ( B ), K 2 [Fe­(C 2 O 4 )­(HPO 4 )­(H 2 O)]·H 2 O ( C ), Na 2 Ba 3 [Fe II 3 (C 2 O 4 ) 6 ] [A IV (C 2 O 4 ) 3 ] (A = Sn, Zr) and Na 2 Ba 3 [Fe II 3 (C 2 O 4 ) 6 ]­[A III (C 2 O 4 ) 3 ] 0.5 [A III (C 2 O 4 ) 2 ] 0.5 (A = Al, Fe) ( D ).…”
mentioning
confidence: 99%
“…Moreover homeleptic and heteroleptic oxalate complexes have been reported as well as complexes with two or more coordinated metal ions, giving rise to a plethora of compounds. Some examples are Na 2 Fe(C 2 O 4 )F 2 , Na 2 Cu(C 2 O 4 ) 2 , Na 2 Cu 2+ (C 2 O 4 ) · 2H 2 O, K 3 [V(C 2 O 4 ) 2 (μ‐SO 4 )] · 2H 2 O, Na 2 Fe 2 (C 2 O 4 ) 3 · 2H 2 O, K 4 Na 2 [Fe(C 2 O 4 ) 2 ] 3 · 3H 2 O, K 2 [Fe(C 2 O 4 )(HPO 4 )(OH 2 )] · H 2 O, Fe 4 (PO 4 )(C 2 O 4 )(H 2 O) 2 , Mn 4 (PO 4 )(C 2 O 4 )(H 2 O) 2 , KFe(C 2 O 4 )F, Li 2 [Fe(C 2 O 4 )Cl 2 ][Fe(C 2 O 4 )(H 2 O) 2 ] · 2H 2 O, and Na 2 Fe(C 2 O 4 )(SO 4 ) · H 2 O . The structures of K 4 Na 2 [Fe(C 2 O 4 ) 2 ] 3 · 3H 2 O, Fe 4 (PO 4 )(C 2 O 4 )(H 2 O) 2 , Mn 4 (PO 4 )(C 2 O 4 )(H 2 O) 2 , KFe(C 2 O 4 )F, and Na 2 Fe(C 2 O 4 )(SO 4 ) · H 2 O are three‐dimensional frameworks.…”
Section: Introductionmentioning
confidence: 99%