A novel diaxially silicon phthalocyanine sensitizer for the generation of high efficiency singlet oxygen in photochemical and sono-photochemical studies

Köse, Gülşah Gümrükçü

doi:10.1016/j.jorganchem.2023.122814

Journal of Organometallic Chemistry

2023

DOI: 10.1016/j.jorganchem.2023.122814

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A novel diaxially silicon phthalocyanine sensitizer for the generation of high efficiency singlet oxygen in photochemical and sono-photochemical studies

Gülşah Gümrükçü Köse

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2024

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Cited by 2 publications

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The Influence of the Isosteric Exchange of Benzene by Thiophene‐Core of Phthalocyanine: The Synthesis, Structure and Opto‐Electronic Behavior of π‐Conjugated Unit Blocks in Materials

Kendrová,

Gašparová,

Andicsová‐Eckstein

et al. 2024

Journal of Heterocyclic Chem

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The strategy of isosteric replacement of the benzene ring with a thiophene core was applied in the design of phthalocyanine 1 with the aim for reaching an effective organic chromophore as employable content in organic photovoltaic devices. The formation of the desired product was not achieved but the approach created organic small‐molecules 2 and 3. These, representing the reactive intermediates, were converted to novel hemiphthalocyanine 4. Although undesired, all exhibit absorbance in the visible region (λmax ~ 400 nm) and proximity of the HOMO/LUMO band edge (Eg: 2.0–3.5 eV), suggesting that compounds 2–4 behaves as an effective π‐conjugated linkers in donor‐π‐acceptor type dyes for dye sensitized solar cells and related high performing energetic devices.

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The Influence of the Isosteric Exchange of Benzene by Thiophene‐Core of Phthalocyanine: The Synthesis, Structure and Opto‐Electronic Behavior of π‐Conjugated Unit Blocks in Materials

Kendrová,

Gašparová,

Andicsová‐Eckstein

et al. 2024

Journal of Heterocyclic Chem

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Advances in upconversion nanomaterials for tumor phototherapy

Bian,

Lu,

Zhou

et al. 2024

Materials Today Communications

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A novel diaxially silicon phthalocyanine sensitizer for the generation of high efficiency singlet oxygen in photochemical and sono-photochemical studies

Cited by 2 publications

References 74 publications

The Influence of the Isosteric Exchange of Benzene by Thiophene‐Core of Phthalocyanine: The Synthesis, Structure and Opto‐Electronic Behavior of π‐Conjugated Unit Blocks in Materials

The Influence of the Isosteric Exchange of Benzene by Thiophene‐Core of Phthalocyanine: The Synthesis, Structure and Opto‐Electronic Behavior of π‐Conjugated Unit Blocks in Materials

Advances in upconversion nanomaterials for tumor phototherapy

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