2007
DOI: 10.1021/es0622195
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A Novel Electro-Fenton Process for Water Treatment:  Reaction-controlled pH Adjustment and Performance Assessment

Abstract: A novel electro-Fenton (E-Fenton) process was developed, in which the desired pH for an effective E-Fenton reaction and for a neutral treated media could be obtained by utilizing the reaction-released H+ and OH- in stead of chemical addition. In the laboratory-scale process using three chambers, the substrate solution pH > 4.0 was designed to be adjusted in situ through three sequencing steps: (I) pH reduction, (II) pH keeping for the effective E-Fenton reaction, and (III) pH recovery to neutral while the E-Fe… Show more

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Cited by 158 publications
(100 citation statements)
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“…In fact the availability of ferrous ions (Fe 2+ ) limits the rate of reaction, but the recycling of Fe from the ferric (Fe Other transition metals like copper, manganese and cobalt are to catalyze this reaction by cycling between oxidized and reduced states [37,38].…”
Section: Trace Elements and Immunitymentioning
confidence: 99%
“…In fact the availability of ferrous ions (Fe 2+ ) limits the rate of reaction, but the recycling of Fe from the ferric (Fe Other transition metals like copper, manganese and cobalt are to catalyze this reaction by cycling between oxidized and reduced states [37,38].…”
Section: Trace Elements and Immunitymentioning
confidence: 99%
“…Advanced oxidation processes such as photocatalytic oxidation, catalytic ozonation, and Fenton oxidation have gained popularity for effective organic destruction from wastewater [3], among which the Fenton reaction has attracted great attention due to its formation of highly potent chemical species, OH, for non-selective oxidation [4,5]. However, the application of homogeneous Fenton reaction is limited by the narrow working pH range (<4), separation and recovery of the iron species [6].…”
Section: Introductionmentioning
confidence: 99%
“…and OH -solution with a known concentration. H 2 O 2 concentration was determined using a UV-VIS spectrophotometer (TU1810, Universal Analysis, Beijing, China) by potassium titanium (IV) oxalate method (Liu et al 2007). pH was monitored with a pH meter (PB-10, Sartorius, Shanghai, China).…”
Section: Methods Of Chemical Analysismentioning
confidence: 99%