A nanocomposite based on carbon paste electrode fabricated, by using zeolite as ion carrier .Functional multi-wall carbon nanotube was used for improvement of electrode response. The optimal composition of CPE was built from 65% graphite powder, 20 wt% paraffin oil, 5% ion carrier (zeolite), 10% MWCNTs. Electrode showed Nernstian response 19.88 (±0.2)mVdecade "1 in the measuring range 10 "7 -10 "2 mol L "1 and showed detection limit of 6.3×10 -7 M. The sensor was successfully used for potentiometric titration Cr 3+ with EDTA. The carbon paste electrode showed fast response time, good selectivity and applicable in the wide pH range of 3 -10.