A novel Fe3+ ions chemosensor by covalent coupling fluorene onto the mono, di- and tri-ammonium functionalized nanoporous silica type SBA-15

Yadavi, Marzieh; Badiei, Alireza; Ziarani, Ghodsi Mohammadi

doi:10.1016/j.apsusc.2013.04.048

Cited by 33 publications

(16 citation statements)

References 39 publications

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“…As a result, NGO exhibited good iron (III) selectivity over other samples (potassium (I), sodium (I), calcium (II), chromium (III), zinc (II), cobalt (II), copper (II), magnesium (II), manganese (II), and molybdenum (VI)), which can be attributed to the high charge densities of iron (III). The charge density of the metal ions is defined as the amount of electric charge/unit volume, which is one of the most important characterizations of the relative electrophilicity of a metal ion . Based on the formal charge and Shannon ionic radius of cations , the charge densities increase in the following order: potassium (I) (0.1) < sodium (I) (0.5) < calcium (II) (0.48) < cobalt (II) (1.15) < zinc (II) (1.18) < manganese (II) (1.65) < copper (II) (1.28) < magnesium (II) (2.5) < chromium (III) (3.12) < molybdenum (VI) (3.75) < iron (III) (6.0).…”

Section: Resultsmentioning

confidence: 99%

N‐butylamine functionalized graphene oxide for detection of iron(III) by photoluminescence quenching

Gholami¹,

Manteghian

Badiei

et al. 2015

Luminescence

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An N-butylamine functionalized graphene oxide nanolayer was synthesized and characterized by ultraviolet (UV)-visible spectrometry, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and transmission electron microscopy. Detection of iron(III) based on photoluminescence spectroscopy was investigated. The N-butylamine functionalized graphene oxide was shown to specifically interact with iron (III), compared with other cationic trace elements including potassium (I), sodium (I), calcium (II), chromium (III), zinc (II), cobalt (II), copper (II), magnesium (II), manganese (II), and molybdenum (VI). The quenching effect of iron (III) on the luminescence emission of N-butylamine functionalized graphene oxide layer was used to detect iron (III). The limit of detection (2.8 × 10(-6) M) and limit of quantitation (2.9 × 10(-5) M) were obtained under optimal conditions.

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Section: Resultsmentioning

confidence: 99%

N‐butylamine functionalized graphene oxide for detection of iron(III) by photoluminescence quenching

Gholami¹,

Manteghian

Badiei

et al. 2015

Luminescence

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“…33 Because of the paramagnetic nature of metal ions, most of these sensors are undergoing a fluorescence quenching mechanism. [29][30][31][32][33] The construction of chemical sensors with fluorescence enhancement in a heterogeneous system is urgently needed.…”

Section: +mentioning

confidence: 99%

Detection and Removal of Hg2+ Based on Mesoporous Silica Material Functionalized by Naphthalimide in Aqueous Solution

Wei

Tan

et al. 2014

ANAL. SCI.

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An inorganic-organic silica material (SBA-15-1), prepared by immobilization of the naphthalimide derivative within the channels of the mesoporous silica material SBA-15, is characterized by several spectroscopic methods. SBA-15-1 can be used as a chemical sensor for detecting and removing Hg 2+ in a heterogeneous system. The fluorescence enhancement of SBA-15-1 was attributed to the formation of a complex between SBA-15-1 and Hg 2+ by a 1:1 complex ratio with the photo-induced electron transfer (PET) being forbidden. The sensor can be applied to the quantification of Hg 2+ with a linear range covering from 1.0 × 10 -7 to 1.0 × 10 -5 M under the neutral condition. Most importantly, the fluorescence changes of the sensor are remarkably specific for Hg 2+ in the presence of other metal ions. Moreover, the response of the sensor toward Hg 2+ is fast and chemically reversible. In addition, the sensor has been used for the determination of Hg 2+ in environmental samples with satisfactory results.

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“…The Literature survey reveals that only limited examples of such hybrid mesoporous chemosensors for Fe 3 þ have been reported [34][35][36].…”

Section: Introductionmentioning

confidence: 99%

A nanostructured LUS-1 based organic–inorganic hybrid optical sensor for highly selective sensing of Fe3+ in water

Karimi

Badiei

Lashgari

et al. 2015

Journal of Luminescence

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A novel Fe3+ ions chemosensor by covalent coupling fluorene onto the mono, di- and tri-ammonium functionalized nanoporous silica type SBA-15

Cited by 33 publications

References 39 publications

N‐butylamine functionalized graphene oxide for detection of iron(III) by photoluminescence quenching

N‐butylamine functionalized graphene oxide for detection of iron(III) by photoluminescence quenching

Detection and Removal of Hg2+ Based on Mesoporous Silica Material Functionalized by Naphthalimide in Aqueous Solution

A nanostructured LUS-1 based organic–inorganic hybrid optical sensor for highly selective sensing of Fe3+ in water

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