A novel 4D fractional-order chaotic entanglement system based on sinusoidal functions is established in this paper. We aim to reveal the relationship between the dynamical behavior of the new system and its entanglement coefficients. It is found that the equilibrium point of the system varies regularly with the successive change of the entanglement coefficient. The supercritical pitchfork bifurcation phenomenon of the new system is discussed based on the fractional-order stability theory. Furthermore, sufficient conditions and threshold for supercritical Hopf bifurcation caused by the entanglement coefficient are provided. Finally, the route to chaos of the new system is explored utilizing multiple numerical indicators, such as spectral entropy complexity, bifurcation diagrams, Lyapunov exponential spectrum, phase portraits, and 0-1 test curves. The results indicate that in addition to various chaotic attractors, there are phenomena such as period-doubling bifurcations, period windows, and coexisting symmetric attractors (periodic or chaotic).