Layered P2-type Na 0.67 MnO 2 , a crucial category of cathode material for sodium-ion batteries (SIBs), faces numerous challenges, including its poor structural stability and Mn 3+ dissolution, which result in an inadequate performance. Herein, the modified Na 0.67 MnO 2 with Co doping was synthesized by the coprecipitation method, which has a hierarchical flake structure consisting of multiple-layer oriented stacking nanosheets. A systematic investigation was conducted to examine the influence of Co doping on the crystal structure and electrochemical performance of Na 0.67 MnO 2 . The optimal Na 0.67 Mn 0.99 Co 0.01 O 2 cathode exhibits an initial discharge specific capacity of 154.3 mA h g −1 at 0.1C within a potential window of 2.0−4.0 V. The Na 0.67 Mn 0.99 Co 0.01 O 2 cathode exhibits a high capacity retention of 90.3% at 1C after 100 cycles and maintains a capacity of 61.2 mA h g −1 even after 500 cycles at 5C. The superior electrochemical performance is derived from reasonable geometrical structure and chemical substitution, which can enhance the interfacial area with the electrolyte and decrease the diffusion energy barrier of sodium ions. This study may provide guidance for designing and constructing stable P2-type Na 0.67 MnO 2 as a high-performance candidate for SIBs.