A novel hydrophobic carborane-hybrid microporous material for reversed C2H6 adsorption and efficient C2H4/C2H6 separation under humid conditions

Wang, Lingyao; Wu, Shuangshuang; Hu, Jianbo; Jiang, Yunjia; Li, Jiahao; Hu, Yongqi; Han, Yan; Ben, Teng; Chen, Banglin; Zhang, Yuanbin

doi:10.1039/d4sc00424h

Chem. Sci.

2024

DOI: 10.1039/d4sc00424h

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A novel hydrophobic carborane-hybrid microporous material for reversed C₂H₆ adsorption and efficient C₂H₄/C₂H₆ separation under humid conditions

Lingyao Wang,

Shuangshuang Wu,

Jianbo Hu

et al.

Abstract: Since ethylene (C2H4) is an important feedstock in the chemical industry, developing economical and energy-efficient adsorption separation techniques based on ethane (C2H6)-selective adsorbents to replace the energy-intensive cryogenic distillation is...

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Cited by 8 publications

References 61 publications

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Elimination of Trace Tetracycline with Alkyl Modified MIL‐101 in Water

Li,

Peng,

et al. 2024

Small

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The overuse of antibiotics poses a serious threat to human health and ecosystems. Therefore, the development of high‐performance antibiotic removal materials has attracted increasing attention. However, the adsorption and removal of trace amounts of antibiotics in aqueous systems still face significant challenges. Taking tetracycline (TC) as a representative antibiotic and based on its structural characteristics, a series of TC adsorbents are prepared by grafting alkyl groups to the framework of MIL‐101(Cr). The adsorptive capacity of the modified materials for tetracycline markedly surpasses that of MIL‐101(Cr), with MIL‐101‐dod achieving the best adsorption performance. MIL‐101‐dod demonstrated an outstanding ability to adsorb tetracycline at low concentrations, where a 5.0 mg sample of MIL‐101‐dod can reduce the concentration of a 90 mL 5 ppm tetracycline solution to below 1 ppb, significantly superior to other sorbents. XPS and IR tests indicate that MIL‐101‐dod has multiple weak interactions with tetracycline molecules, including C─H…O and C─H…π. This work provides theoretical and experimental support for the development of adsorbents for low‐concentration antibiotics.

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Elimination of Trace Tetracycline with Alkyl Modified MIL‐101 in Water

Li,

Peng,

et al. 2024

Small

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Boosting C2H6/C2H4 separation via the precise electrostatic modulation of synthetic 1D channel at atomic level

Ainiwaner,

Huang,

Zheng

et al. 2024

Nano Res.

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Chemistry of three-dimensional icosahedral boron clusters anions: closo-dodecaborate (2-) [B12H12]2- and carba-closo-dodecaborate(-) [CB11H12]-

Wang,

Jiang,

Duttwyler

et al. 2024

Coordination Chemistry Reviews

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A novel hydrophobic carborane-hybrid microporous material for reversed C₂H₆ adsorption and efficient C₂H₄/C₂H₆ separation under humid conditions

Abstract: Since ethylene (C2H4) is an important feedstock in the chemical industry, developing economical and energy-efficient adsorption separation techniques based on ethane (C2H6)-selective adsorbents to replace the energy-intensive cryogenic distillation is...

Cited by 8 publications

References 61 publications

Elimination of Trace Tetracycline with Alkyl Modified MIL‐101 in Water

Elimination of Trace Tetracycline with Alkyl Modified MIL‐101 in Water

Boosting C2H6/C2H4 separation via the precise electrostatic modulation of synthetic 1D channel at atomic level

Chemistry of three-dimensional icosahedral boron clusters anions: closo-dodecaborate (2-) [B12H12]2- and carba-closo-dodecaborate(-) [CB11H12]-

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