Loose-leaf textbook is a new type of textbook in the new era of education environment, which has better interactivity and flexibility of use than traditional textbooks. In order to improve effect analysis of teaching with loose-leaf textbooks, a multi-dimensional evaluation method of teaching with loose-leaf textbooks based on the improved K-modes algorithm is designed. In the process, the multi-dimensional evaluation system of teaching using loose-leaf textbooks is constructed by combining objective and subjective directions, and the corresponding index value calculation method is designed, and then the data processing of multi-dimensional evaluation based on the improved K-modes algorithm is optimised by introducing the error sum of squares and the co-presence rate to optimise the clustering process, so as to obtain a complete multi-dimensional evaluation method. Results show that the research method maintains the accuracy rate above81.2% when the number of sample points increases to 1200 when performing data classification accuracy analysis; when generating the multidimensional evaluation results, the research method generates realistic evaluation results for 8indicators. It shows that the research method can effectively carry out the multidimensional evaluation of teaching using loose-leaf textbooks, and can provide certain technical references to the education industry.