“…Having a pure calcium carbonate system with no chemical heterogeneity, the partitioning of the porous medium is only due to the physical heterogeneity at pore scale (fracture/matrix), and therefore, no localization of reactions is assumed. We consider one immobile zone only, to align the formulation with the timeâdependent singleârate mass transfer model as opposed to multiple rate mass transfer model where multiple mass transfer processes occur simultaneously in a porous medium (see, e.g., FernandezâGarcia & SanchezâVila, ; Geiger et al, ; Maier et al, ; SolerâSagarra et al, ; Tecklenburg et al, ). As such equation (3) can be rewritten as …”