A novel Pebax-C60(OH)24/PAN thin film composite membrane for carbon dioxide capture

Wu, Yongdong; Zhao, Dan; Ren, Jizhong; Qiu, Yongtao; Deng, Mingke

doi:10.1016/j.seppur.2018.12.073

Cited by 39 publications

(15 citation statements)

References 40 publications

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“…Oppositely, the characteristic peak intensity of NaY increases at the same time. These results validate that the zeolite disturbs the molecular accumulation and the interaction of inter‐ & intra‐molecular chains of Pebax . Consequently, it would produce more proportion of amorphous structure with less compactness, which is favorable for increasing the free fractional volume of membranes .…”

Section: Resultssupporting

confidence: 61%

Preparation and characterization of CO₂‐selective Pebax/NaY mixed matrix membranes

Zheng

Zhang

et al. 2019

J of Applied Polymer Sci

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CO 2 -selective Pebax/NaY mixed matrix membranes (MMMs) were prepared by incorporating NaY zeolite into Pebax matrix. The morphology, chemical groups, thermal stability, and microstructure of the MMMs were investigated by scanning electron microscope, Fourier transform infrared spectroscopy, thermogravimetric analysis, and X-ray diffraction, respectively. The effects of zeolite loading amount, permeation temperature and pressure on the CO 2 /N 2 separation performance of the resultant membranes were studied. The as-prepared MMMs are much superior to the pristine Pebax membranes in terms of permeability and selectivity. The CO 2 permeability and CO 2 /N 2 selectivity can respectively reach to 131.8 Barrer and 130.8 for MMMs made by the starting materials containing 40 wt % NaY.

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Section: Resultssupporting

confidence: 61%

Preparation and characterization of CO₂‐selective Pebax/NaY mixed matrix membranes

Zheng

Zhang

et al. 2019

J of Applied Polymer Sci

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“…The neat and MMMs exhibited a broad peak at around 20.7° and a comparatively narrow diffraction peak in the region of 24.0° corresponding to the soft PE segments and hard PA segments of Pebax with d ‐spacing of 4.36 and 3.70 Å, respectively. The narrow peak at 24° is the characteristic peak of the Pebax and reported in literature [51,52] . It is interesting to note that, initially the addition of g ‐PTAP (wt.…”

Section: Resultssupporting

confidence: 60%

“…The FT‐IR spectra of TAP and g ‐PTAP are shown in Figure 3A. The peaks in the region of 1200–1600 cm −1 and 3000–3500 cm −1 are attributed to C−N heterocyclic and the stretch vibration of ‐NH, respectively [52–54] . The presence of coupled doublet bands at around 3420 cm −1 and 3310 cm −1 are related to NH‐stretching vibrations while the peaks at 3070 cm −1 is due to aromatic C−H stretch.…”

Section: Resultsmentioning

confidence: 99%

A 2D Graphitic‐Polytriaminopyrimidine (g‐PTAP)/Poly(ether‐block‐amide) Mixed Matrix Membrane for CO₂ Separation

Asim

Khan

Helal

et al. 2021

Chemistry An Asian Journal

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Poly(ether‐block‐amide)/g‐PTAP mixed matrix membranes (MMMs) were developed by incorporating different wt.% (1–10%) of a novel 2D g‐PTAP nanofiller and its effects on membrane structure and gas permeability were studied. The novel 2D material g‐PTAP was synthesized and characterized by various analytical techniques including field‐emission scanning electron microscopy (FESEM), X‐ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and Raman spectroscopy. The fabricated MMMs were investigated to study the interaction and compatibility between Pebax and g‐PTAP. The MMMs showed an effective integration of g‐PTAP nanofiller into the Pebax matrix without affecting its thermal stability. Gas permeation experiments with MMMs showed improved CO2 permeability and selectivity (CO2/N2) upon incorporation of g‐PTAP in the Pebax polymer matrix. The maximum CO2 permeability enhancement from 82.3 to 154.6 Barrer with highest CO2/N2 selectivity from 49.5 to 83.5 were found with 2.5 wt.% of nanofiller compared to neat Pebax membranes.

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“…The PI-COOH/UiO-66/Cu 2+ TFN membranes have a high CO 2 /CH 4 selectivity (29–35) as well as high CO 2 permeance (109–350 GPU). In comparison to some polymer-based and novel material-based membranes (such as Matrimid 5218, cellulose acetate, 6FDA-BAPAF, SILMS, and SAPO), PI-COOH/UiO-66/Cu 2+ membranes show both higher CO 2 /CH 4 selectivity and higher CO 2 permeance. − Although the Kapton, PU/PVAc (80/20), and MOF-based membranes such as ZIF-8, UiO-66, and MIL-101(Zr) exhibit high CO 2 /CH 4 selectivity, their low CO 2 permeance (<10 GPU) reduces their overall separation performance. ,, The comprehensive separation performance of the PI-COOH/UiO-66/Cu 2+ TFN membranes is better than that of the most TFN membranes reported in the literature, including PA/CDC, Matrimid/Cu 3 (BTC) 2 , PIM-1/GO, Pebax 1657/C 60 (OH) 24 , and PDMS/zeolite 4 Å. ,− …”

Section: Resultsmentioning

confidence: 99%

Thin Films Based on Polyimide/Metal–Organic Framework Nanoparticle Composite Membranes with Substantially Improved Stability for CO₂/CH₄ Separation

Zhu

et al. 2022

ACS Appl. Nano Mater.

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As one of the gas separation membranes, the thin-film nanocomposite (TFN) membrane can effectively reduce gas transport resistance and improve gas permeance. However, due to the high mobility of the chain in the thin film, it is still a great challenge to realize the TFN membrane with stable separation performance. In this work, we report a less destructive and efficient cross-linking strategy based on metal-ion coordination to improve the stability of the TFN membrane for CO2/CH4 separation. The selective layer is made of carboxylated polyimide as a matrix and UiO-66 nanoparticles (diameters of ∼50 nm) as fillers. By simply immersing TFN membranes in Cu(NO3)2 solution, coordination bonds are successfully constructed between Cu2+ and carboxyl groups (−COOH). The cross-linked TFN membranes exhibit high CO2/CH4 selectivity of up to 29–35 with CO2 permeance of 110–350 GPU, outperforming most previously reported membranes. Moreover, the plasticization pressure of the cross-linked membranes improves from 0.3–0.9 to 0.9–1.5 MPa, higher than most reported asymmetric and hollow fiber membranes. In the CO2/CH4 (50:50 v/v) mixed-gas permeation tests, the cross-linked membranes retain constant CO2/CH4 selectivity at 23.9–25.2 with increasing mixed-gas feed pressure. The cross-linked membranes also demonstrate stable CO2/CH4 selectivity in the range of 27.2–31.2 within 100 h of testing time under a 1.0 MPa CO2 partial pressure.

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A novel Pebax-C60(OH)24/PAN thin film composite membrane for carbon dioxide capture

Cited by 39 publications

References 40 publications

Preparation and characterization of CO₂‐selective Pebax/NaY mixed matrix membranes

Preparation and characterization of CO₂‐selective Pebax/NaY mixed matrix membranes

A 2D Graphitic‐Polytriaminopyrimidine (g‐PTAP)/Poly(ether‐block‐amide) Mixed Matrix Membrane for CO₂ Separation

Thin Films Based on Polyimide/Metal–Organic Framework Nanoparticle Composite Membranes with Substantially Improved Stability for CO₂/CH₄ Separation

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A novel Pebax-C60(OH)24/PAN thin film composite membrane for carbon dioxide capture

Cited by 39 publications

References 40 publications

Preparation and characterization of CO2‐selective Pebax/NaY mixed matrix membranes

Preparation and characterization of CO2‐selective Pebax/NaY mixed matrix membranes

A 2D Graphitic‐Polytriaminopyrimidine (g‐PTAP)/Poly(ether‐block‐amide) Mixed Matrix Membrane for CO2 Separation

Thin Films Based on Polyimide/Metal–Organic Framework Nanoparticle Composite Membranes with Substantially Improved Stability for CO2/CH4 Separation

Contact Info

Product

Resources

About

Preparation and characterization of CO₂‐selective Pebax/NaY mixed matrix membranes

Preparation and characterization of CO₂‐selective Pebax/NaY mixed matrix membranes

A 2D Graphitic‐Polytriaminopyrimidine (g‐PTAP)/Poly(ether‐block‐amide) Mixed Matrix Membrane for CO₂ Separation

Thin Films Based on Polyimide/Metal–Organic Framework Nanoparticle Composite Membranes with Substantially Improved Stability for CO₂/CH₄ Separation