A Novel Route To Molecular Self-Assembly: Self-Intermixed Monolayer Phases

Wild, Michael de; Berner, Simon; Suzuki, Hitoshi; Yanagi, Hisao; Schlettwein, Derck; Ivan, Stanislav; Baratoff, A.; Guentherodt, H.-J.; Jung, Thomas A.

doi:10.1002/1439-7641(20021018)3:10<881::aid-cphc881>3.0.co;2-p

Cited by 131 publications

(93 citation statements)

References 11 publications

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“…14c) [86]. Moreover, when subPc is coadsorbed with C 60 on Ag(111), chiral pinwheels are formed in a dense packing [87]. Three C 60 units are surrounded by three subPC molecules, and six of these pinwheels form a hexagon.…”

Section: Perturbation Of Parity Eigenstates In 1927mentioning

confidence: 99%

Molecular chirality at surfaces

Ernst

2012

Physica Status Solidi (b)

223

264

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With the adsorption of larger molecules being increasingly tackled by surface scientists, the aspect of chirality often plays a role. This paper gives a topical review of molecular chirality at surfaces and gives a phenomenological overview of different aspects of adsorption and self‐assembly of chiral and prochiral molecules and the principles of mirror‐symmetry breaking at a surface. After a brief introduction into the history of molecular chirality and the important role it played for understanding the spatial structure of molecules, definitions of chirality are presented. Topics treated here are principle ways to create single chiral adsorbates, chiral ensembles, and monolayers by achiral molecules, adsorption of intrinsically chiral molecules at achiral and chiral surfaces, long‐range symmetry breaking in two‐dimensional (2D) crystals due to additional chiral bias, chiral restructuring of solid surfaces under the influence of chiral molecules, switching the handedness of adsorbates, and chirality at the liquid/air interface. An outlook onto further potential research directions and recommendations for further reading, including nonsurface‐related sources of chiral topics completes this paper.

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Section: Perturbation Of Parity Eigenstates In 1927mentioning

confidence: 99%

Molecular chirality at surfaces

Ernst

2012

Physica Status Solidi (b)

223

264

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“…To date there have been no reports of phthalocyaninefullerene cocrystallates, although scanning tunneling microscopy (STM) imaging of Cu(phthalocyanine) 15 and B(subphthalocyanine) 16 on a close-packed C 60 film has been investigated.…”

Section: Fullerene-porphyrin and Fullerene-metalloporphyrin Cocrystalmentioning

confidence: 99%

Fullerene—Porphyrin Constructs

Boyd

Reed

2005

ChemInform

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Porphyrins and fullerenes are spontaneously attracted to each other. This new supramolecular recognition element can be used to construct discrete host-guest complexes, as well as ordered arrays of interleaved porphyrins and fullerenes. The fullereneporphyrin interaction underlies successful chromatographic separations of fullerenes, and there are promising applications in the areas of porous framework solids and photovoltaic devices.

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“…4. 21) These epochal works triggered a variety of hydrogen-bond-based molecular architectures on surfaces, such as one-dimensional chains, [22][23][24] porous networks, [25][26][27][28][29][30][31] guest-host assemblies, 25,26,29,32) and multiple component (binary [33][34][35][36][37][38][39][40][41] and ternary 29,42) ) assemblies. Beton and coworkers proved that 2D hexagonal networks with regular-size pores can be produced by a combination of perylene derivatives and melanine.…”

Section: On-surface Selective Hydrogen Bond Networkmentioning

confidence: 99%

“…Subphthalocyanine (SubPc) and C 60 molecules formed well-mixed phases on a Ag(111) surface. 33) It is noteworthy that the assembling behavior depended on the mixing ratio (SubPc:C 60 ). The 2 : 3 and 1 : 1 ratios formed "stripe" and "star" phases, respectively.…”

Section: On-surface Selective Hydrogen Bond Networkmentioning

confidence: 99%

On-surface molecular nanoarchitectonics: From self-assembly to directed assembly

Wakayama

2016

Jpn. J. Appl. Phys.

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The rogress of on-surface molecular nanoarchitectonics over the last two decades has been reviewed. Over the early period in the 1990s-2000s, molecular self-assemblies were intensively studied, where van der Waals (vdW) interaction was predominant. After that, in the 2000s, selective intermolecular interactions based on hydrogen bonds and metal-molecule coordination enabled one to direct the assembling behaviors. Here, the concept of this directed assembly is opposite to that of the vdW-based self-assembly because the resulting architectures are purposefully tailored by programing intermolecular interaction. These efforts brought forth fruit in the on-surface syntheses of covalent bond networks. Particularly in the 2010s, on-surface covalent coupling was applied to graphene nanoribbons, where widths and edge structures can be precisely defined on the atomic scale. These works have the potential to bridge fundamental material nanoarchitectonics and functional device fabrication. In this paper, such a historical development of on-surface molecular nanoarchitectonics is reviewed, with the specific emphasis on the superiority of scanning tunneling microscopy.

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A Novel Route To Molecular Self-Assembly: Self-Intermixed Monolayer Phases

Cited by 131 publications

References 11 publications

Molecular chirality at surfaces

Molecular chirality at surfaces

Fullerene—Porphyrin Constructs

On-surface molecular nanoarchitectonics: From self-assembly to directed assembly

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