Original scientific paper https://doi.org/10.2298/TSCI191113107PIn order to realize the continuous stability of photovoltaic power generation system and the controllability of thermal energy storage, a photovoltaic fuel cell combined power generation system consisting of photovoltaic cell array, proton exchange membrane fuel cell, alkaline electrolysis cell and super capacitor is proposed. The system, at the same time, establishes the mathematical model of its various components and the system cost model, designs the thermal energy distribution of the thermal energy storage management coordination system, and uses the high efficiency battery to meet the load requirements of the power system. In addition, the paper uses simulation technology as a research method to build a simulation model of hybrid fuel cell thermal energy storage control and power generation system, and analyzes the system's thermal energy supply and demand balance. The simulation results confirm that the photovoltaic fuel cell hybrid power generation system has high economic performance, can meet the user's power and thermal energy requirements, and realizes the requirement of completely independent power supply.