A novel ZIF-8 and ZIF-67 co-modified TiO2 nanospheres for highly efficient degradation of methylene blue under simulated sunlight

Cai, Hanyong; Gao, Juan; Deng, Jiale; Zheng, Lingcheng; Liu, Mei; Wei, Pingping; Wang, Yanfen; Li, Yang

doi:10.1007/s10854-023-11697-9

J Mater Sci: Mater Electron

2023

DOI: 10.1007/s10854-023-11697-9

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A novel ZIF-8 and ZIF-67 co-modified TiO2 nanospheres for highly efficient degradation of methylene blue under simulated sunlight

Hanyong Cai,

Juan Gao,

Jiale Deng

et al.

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Cited by 4 publications

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Photocatalytic Degradation of Methylene Blue by Engineering Tungstic Acid@ZIF‐67 Cocatalyst

Rasheed,

Khan,

Nazir

et al. 2024

ChemistrySelect

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The zeolitic imidazolate frameworks have gained significant attention in various applications owing to their exceptional surface area, customizable porosity, and excellent thermal and chemical stability, making them a remarkable nanomaterial. The present study involved the utilization of ultrasonic‐assisted techniques to integrate tungstic acid into the zeolitic imidazolate framework (TA@ZIF‐67) with the aim of augmenting the photocatalytic activity. The as‐synthesized nanocomposite was characterized using X‐ray diffraction and scanning electron microscopic analysis to inspect the structural aspects and morphology. The reduction in particle size of TA@ZIF‐67 due to the incorporation of tungstic acid results in a higher surface area, leading to a significant improvement in the photocatalytic activity of ZIF‐67. The assessment of the photocatalytic performance of ZIF‐67 and TA@ZIF‐67 was conducted through the degradation of methylene blue (MB) under sunlight. The degradation efficiency of ZIF‐67 and TA@ZIF‐67 was observed to be 61% and 85%, respectively, of the MB solution following a 60 min irradiation period. The investigation of the kinetics study based on rate constant values revealed that the utilization of TA@ZIF‐67 presented a greater efficiency in the removal of MB from an aqueous solution. The results pave a new avenue toward the design of MOF‐based photocatalysts for water treatments.

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Photocatalytic Degradation of Methylene Blue by Engineering Tungstic Acid@ZIF‐67 Cocatalyst

Rasheed,

Khan,

Nazir

et al. 2024

ChemistrySelect

View full text Add to dashboard Cite

show abstract

Facile synthesis of Ni-ZIF-8 with improved photodegradation performance for methylene blue

Zulfa,

Hidayat,

Utomo

et al. 2024

Case Studies in Chemical and Environmental Engineering

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Performance of Ti/TiO2-ZIF-67 photoanode under LED irradiation applied to the photoelectrodegradation of the antidepressant venlafaxine (VEN) in municipal wastewater effluent

Irikura,

Rojas-Mantilla,

Ayala-Durán

et al. 2025

Journal of Environmental Management

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A novel ZIF-8 and ZIF-67 co-modified TiO2 nanospheres for highly efficient degradation of methylene blue under simulated sunlight

Cited by 4 publications

References 72 publications

Photocatalytic Degradation of Methylene Blue by Engineering Tungstic Acid@ZIF‐67 Cocatalyst

Photocatalytic Degradation of Methylene Blue by Engineering Tungstic Acid@ZIF‐67 Cocatalyst

Facile synthesis of Ni-ZIF-8 with improved photodegradation performance for methylene blue

Performance of Ti/TiO2-ZIF-67 photoanode under LED irradiation applied to the photoelectrodegradation of the antidepressant venlafaxine (VEN) in municipal wastewater effluent

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