A “one-for-three” strategy through a facile one-step hydrothermal engineering of commercial MoO₃ for high-performance proton storage

Abstract

The sluggish diffusion kinetics of metal ions and irreversible structure transition of electrode materials lead to serious decay of electrochemical performance. In this work, a “one-for-three” strategy is demonstrated to...

A high voltage aqueous proton battery using an optimized operation of a MoO3 positive electrode

“…70%. The optimization of the material morphology, 23 positive–negative mass ratio, cell fabrication process and cut-off voltage could improve the slight capacity decrease during cycling. The cell keeps the coulombic efficiency over 98% until the 50th cycle.…”

Intercalation Reaction of Molybdenum Trioxide Cathode for Rechargeable Ion Batteries

“…[48] The polymer is a conductive and buffering agent to alleviate the structural fragmentation of MoO 3 during the cycle effectively. Liu et al [107] prepare polyaniline coated with MoO 3 by a simple one-step hydrothermal process. A thin layer of polyaniline (PANI) coated MoO 3 introduces oxygen vacancies and inhibits the dissolution of MoO 3 .…”

“…Composite with polymers is one of the effective strategies to enhance MoO 3 ‐based cathodes with structural stability and conductivity. The selection of polymers includes polyaniline (PANI), [107] poly (ethylene oxide) (PEO), [108] polypyrrole (PPy), [109] polyethylene glycol (PEG) [48] . The polymer is a conductive and buffering agent to alleviate the structural fragmentation of MoO 3 during the cycle effectively.…”

Construction of Three-Dimensional Co(PO3)2/Cu3P Heterostructure for High-Rate Supercapacitors

“…To meet the rapid development of high-speed electric vehicles and other high power devices, supercapacitors are highly desirable and attractive due to the fast charge/discharge rate, high power density, and superior cycling performance. − Although carbon materials have been widely used in supercapacitors through electrical double layer capacitor behavior, − the low specific capacitance and limited energy density hinder their electrochemical performance. Pseudocapacitive or battery-type materials, such as metal oxides/sulfides/hydroxides (M-O/M-S/M-OH) based on Faraday redox reactions, exhibit much higher theoretical capacitance than carbon-based materials. − However, the electrochemical performance, especially the rate capability, still does not meet the expectation due to the poor electronic conductivity and sluggish reaction kinetics. , …”