A one-pot synthesis of micron-sized and nanoscale poly(N-acryloxysuccinimide-co-N-vinylpyrrolidone) particles

DePorter, Sandra M.; Hendricks, Noah; Gray, Melissa A.; McNaughton, Brian R.

doi:10.1016/j.tetlet.2012.09.052

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Free Radical Polymerization For Homopolymers and Statistical1

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2015

2024

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Cited by 2 publications

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“…38 Aminolysis of NHS-ester groups within the brush with various n-alkylamines were studied by infrared and surface plasmon spectroscopy. Using inverse microemulsion/ free radical polymerization, 39 reactive microparticles of copolymer, poly(NHSA-co-NVP), were prepared in one pot that could be coupled with amine-functionalized dye to generate fluorescent particles.…”

Section: Free Radical Polymerization For Homopolymers and Statisticalmentioning

confidence: 99%

Activated Ester Containing Polymers: Opportunities and Challenges for the Design of Functional Macromolecules

2015

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Section: Free Radical Polymerization For Homopolymers and Statisticalmentioning

confidence: 99%

Activated Ester Containing Polymers: Opportunities and Challenges for the Design of Functional Macromolecules

2015

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Silver-Mediated ARGET-ATRP of Reactive Acrylates Using TPMA^NMe2 Ligand: A Universal Strategy for Controlled Copolymerization

Weingarten,

Adams

2024

ACS Macro Lett.

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A controlled polymerization using activated acrylate monomers via ARGET-ATRP is developed with a tris[(4-dimethylamino pyridyl)methyl]amine ligand to address issues with weaker ligands and monomers that can undergo postpolymerization functionalization. This catalyst system enables the polymerization of N-acryloxy succinimide, fluorinated monomers, and isocyanato ethyl acrylate under controlled homogeneous conditions, ensuring linear molecularweight growth and low polydispersity. Two block copolymerization strategies produce amphiphilic copolymers with narrow molecular-weight distributions and customizable compositions, allowing for various postpolymerization functionalizations.

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A one-pot synthesis of micron-sized and nanoscale poly(N-acryloxysuccinimide-co-N-vinylpyrrolidone) particles

Cited by 2 publications

References 11 publications

Activated Ester Containing Polymers: Opportunities and Challenges for the Design of Functional Macromolecules

Activated Ester Containing Polymers: Opportunities and Challenges for the Design of Functional Macromolecules

Silver-Mediated ARGET-ATRP of Reactive Acrylates Using TPMA^NMe2 Ligand: A Universal Strategy for Controlled Copolymerization

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A one-pot synthesis of micron-sized and nanoscale poly(N-acryloxysuccinimide-co-N-vinylpyrrolidone) particles

Cited by 2 publications

References 11 publications

Activated Ester Containing Polymers: Opportunities and Challenges for the Design of Functional Macromolecules

Activated Ester Containing Polymers: Opportunities and Challenges for the Design of Functional Macromolecules

Silver-Mediated ARGET-ATRP of Reactive Acrylates Using TPMANMe2 Ligand: A Universal Strategy for Controlled Copolymerization

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Product

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Silver-Mediated ARGET-ATRP of Reactive Acrylates Using TPMA^NMe2 Ligand: A Universal Strategy for Controlled Copolymerization