After the successful investigation and confirmation of non zero θ P M N S 13by various experiments, we are standing at a square where we still encounter a number of issues, which are to be settled. In this paper, we have extended our recent work towards a precise prediction of the θ P M N S 23 mixing angle, taking into account the neutrino mass hierarchy. We parameterize the non-trivial correlation between quark (CKM) and lepton (PMNS) mixing matrices in quarklepton complementarity (QLC) model as Vc = UCKM .ψ.UP M N S , where ψ is a diagonal phase matrix. Monte Carlo simulations are used to estimate the texture of Vc and compare the results with the standard Tri-Bi-Maximal (TBM) and Bi-Maximal(BM) structures of neutrino mixing matrix. We have predicted the value of θ P M N S 23 for normal and inverted neutrino mass hierarchies. The value of θ P M N S 23 obtained for two cases are about 1.3σ away from each other, implying the better precision can give us a strong hint for the type of neutrino mass hierarchy.We use the QLC model, where the non trivial relation between the U P M N S and U CKM mixing matrix is taken as the phase mismatch between quark and leptons, via ψ the diagonal matrix. After following the model procedure the central values obtained for θ P M N S 23 are 44.24 • and 47.16 • for normal and inverted neutrino mass hierarchies respectively. It has been noticed that the precise values of θ P M N S 23 thus obtained for the two cases, NH and IH are about 2σ and 3σ away from our previously obtained result [8], which can give a strong hint for the hierarchy of neutrino masses.As such, in future the better precision of θ P M N S 23 can give the strong hint about the neutrino mass hierarchy.