A pentafluorosulfur .beta.-sultone and some derivatives

Canich, J. M.; Ludvig, Maria M.; Gard, Gary L.; Shreeve, Jean’ne M.

doi:10.1021/ic00194a001

Cited by 43 publications

(11 citation statements)

References 3 publications

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“…The composition of the products was confirmed by elemental and X-ray structure analysis (see below). The expected adducts EM(OrBu), (6,7,8,9 ) were, on the other hand, isolated in the case of the other alkali metal tert-butoxides. All adducts were slightly soluble in benzene and exhibited only one signal in their 'H N M R spectra.…”

Section: Resultsmentioning

confidence: 94%

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Synthesis and Structures of Alkali(alkoxy) Antimonates and Bismuthates

Veith

Hüch

1995

Chemistry A European J

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As(OtBu), does not form adducts with alkali metal tert-butoxides MOtBu (M = Li, Na, K. R b and Cs), whereas the corresponding Sb(OrBu), (2) and Bi(OtBu), (3) react with MOtBu (M = K, Rb. Cs) to yield M(OtBu),Sb (M = K ( 6 ) . R b (7), Cs (8)) and M ( 0 -tBu),Bi (M = 9 ) , respectively. X-ray structure determinations for 6 and 9 show them to be one-dimensional coordination polymers composed of E(OtBu), (E = Sb. Bi) units linked through potassium atoms. These E(OIBU), units display a $-trigonal-bipyramidal coordination around the metal atom ( S b -0 =1.971 (2) and 2.181(2) A, Bi-0 = 2.068(8) and 2.275(8) A). Both the structures exhibit a planar four-coordinate environment of oxygen around the potassium atoms ( K -0 = 2.650(2)-2.967(2)

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Section: Resultsmentioning

confidence: 94%

“…[t91 A section of the crystal structures of compounds KSb(OtBu), (6) and KBi(OfBu), (9) are displayed in Figures 1 and 2. Although these two compounds have identical stoichiometry.…”

Section: Crystal Structuresmentioning

confidence: 99%

Synthesis and Structures of Alkali(alkoxy) Antimonates and Bismuthates

Veith

Hüch

1995

Chemistry A European J

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“…Most of the reactions of the epoxide F5SCFCF20 (54 ) were not quantitatively analyzed because of the impossibility of separating the products that were formed.…”

Section: Chapter III T Imentioning

confidence: 99%

Chemistry of Pentafluorothio (SF5) Alkyl Derivatives

Winter¹

2000

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“…The resulting sulfonyl fluoride can then be treated with base and acidified to give SF 5 CHFS0 2 0H. 84 16 ( 6) The sulfonyl fluoride was later treated with fluorine:…”

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Synthesis and Characterization of some Flourine-containing Lithium Alkyl Sulfonates: Flourinated Sulfonates and SF5-containing Sulfonates

Ullrich¹

2000

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A pentafluorosulfur .beta.-sultone and some derivatives

Cited by 43 publications

References 3 publications

Synthesis and Structures of Alkali(alkoxy) Antimonates and Bismuthates

Synthesis and Structures of Alkali(alkoxy) Antimonates and Bismuthates

Chemistry of Pentafluorothio (SF5) Alkyl Derivatives

Synthesis and Characterization of some Flourine-containing Lithium Alkyl Sulfonates: Flourinated Sulfonates and SF5-containing Sulfonates

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