Harnessing non-spatial properties of photons as if they represent an additional independent coordinate underpins the emerging synthetic dimension approach. It enables probing of higher-dimensional physical models within low-dimensional devices, such as on a planar chip. We demonstrate an integrated thin-film lithium niobate ring resonator that, under dynamic modulation, simulates a tight-binding model with its discrete frequency modes representing lattice sites. Inter-mode coupling, and the simulated lattice geometry, can be reconfigured by controlling the modulating signals. Up to a quasi-3D lattice connectivity with controllable gauge potentials has been achieved by simultaneous synchronized nearest-, second- and third-nearest-neighbor coupling, and verified by acquiring time-resolved synthetic band structures. Development of synthetic frequency dimension devices in the thin-film lithium niobate photonic integration platform is a key step in increasing the complexity of topological models achievable on a chip, combining efficient electro-optic mode coupling response with non-linear effects for long-range mode interactions.