“…Vacancy concentration in Fe deformed 20% at room temperature was reported to be at the order of 10 −5 [1], which is obviously far beyond the thermal equilibrium concentration. There have been a wide variety of studies on the effect of excess vacancies on diffusion [2,3], nucleation of precipitate [4], recrystallisation [5], movement of grain boundaries [6,7], creep deformation [8], generation of nano-voids [9][10][11], fatigue crack initiation in persistent slip bands [12][13][14][15] and strain localisation and plastic instability [16][17][18]. Interactions between hydrogen and vacancy [19,20], or hydrogen-vacancy complex and dislocations [21] are other points of current discussion.…”