A Poly(carbazole-alt-triazole) with Thiabendazole Side Groups as an “On-Off-On” Fluorescent Probe for Detection of Cu(II) Ion and Cysteine

Abstract

A novel conjugated polymer PCZBTA-TBZ containing thiabendazole as recognition unit was synthesized via Suzuki coupling reaction, and its structural characterization, spectroscopic analysis and photophysical properties were investigated. In the metal ion response study, the addition of Cu 2+ led to the occurrence of the PET mechanism, which signi cantly quenched the uorescence of the polymer PCZBTA-TBZ with a quenching effect of 98%. According to the density functional theory calculation, compared with other polycarbazoles or other alternative copolymers containing carbazole, with alternating carbazole and triazole enhances the electron mobility and reduces the energy band gap of the polymer. Due to the strong coordination ability between Cu 2+ and Cys, the adding Cys competes the Cu 2+ in the [PCZBTA-TBZ-Cu 2+ ] complex, blocking the occurrence of PET, and the uorescence intensity of PCZBTA-TBZ is restored. The addition of other amino acids caused almost no change. The polymer is expected to be used for dual uorescence detection of speci c metal ions and Cys.

Synergistic Influence of FRET on a High Quantum Yield π- Conjugate Polycarbazole-ZnS Composite Thin Film

“…To calculate the fluorescence quantum yield of synthesized materials, a relative technique is used, with quinine sulfate serving as the reference dye. The following equation is used for the calculation of the quantum yield ϕ false( PL false) = ϕ false( normalr false) A normalr A normals F normals F normalr n normals n normalr …”