A Polymer‐Bound Monodentate‐P‐Ligated Palladium Complex as a Recyclable Catalyst for the Suzuki–Miyaura Coupling Reaction of Aryl Chlorides

Abstract

At hree-foldc ross-linked polymer-bound phosphine(POL-Ph 3 P) with high phosphorus content has been prepared. Thep hosphorus-containingp olymer forms am onodentate-P-ligated palladium complex, which shows excellent activity in SuzukiMiyaura cross-coupling reactions of aryl chlorides. Importantly,t he catalyst Pd/POL-Ph 3 Pi sh ighly stable and can be reused for at least 10 times without losing reactivity.

Highly efficient palladium catalysts supported on nitrogen contained polymers for Suzuki-Miyaura reaction

“…It is highly desirable to develop efficient heterogeneous Pd catalysts for Suzuki-Miyaura reaction. Some heterogeneous Pd catalysts had been developed by immobilizing Pd particles on supports, such as on oxides [14], polymers [15][16][17][18][19][20][21], carbon nanotubes [22], magnetic nanomaterials [23], and silica [24]. Unfortunately, heterogeneous Pd catalysts are generally less active than homogeneous Pd catalysts for Suzuki-Miyaura reaction.…”

Carbonylative Suzuki coupling and alkoxycarbonylation of aryl halides using palladium supported on phosphorus‐doped porous organic polymer as an active and robust catalyst

“…In recent years, a series of POPs containing PPh 3 ligand and its derivatives, have been successfully prepared and applied as the catalysis supports for immobilizing transition metal species . Due to the strong interaction between transition metals and phosphine ligands, these catalysts usually exhibited high catalytic activities, long‐term reusability and excellent leaching resistant ability . Some of them even outperformed the activities of their homogeneous analogues .…”

“…Due to the strong interaction between transition metals and phosphine ligands, these catalysts usually exhibited high catalytic activities, long‐term reusability and excellent leaching resistant ability . Some of them even outperformed the activities of their homogeneous analogues . Although the applications of phosphine functionalized POPs in non‐carbonylative cross‐coupling reactions of aryl halides have been widely investigated in recently years, studies of their catalytic applications in carbonylation of aryl halides were relatively unexplored …”

“…Some of them even outperformed the activities of their homogeneous analogues . Although the applications of phosphine functionalized POPs in non‐carbonylative cross‐coupling reactions of aryl halides have been widely investigated in recently years, studies of their catalytic applications in carbonylation of aryl halides were relatively unexplored …”

Iridium Supported on Phosphorus‐Doped Porous Organic Polymers: Active and Recyclable Catalyst for Acceptorless Dehydrogenation and Borrowing Hydrogen Reaction

“…[2] Therefore, POPs possess high specific surface areas, thus enabling their excellent thermal and chemical stability, and the ability to endure harsh reaction conditions. In the recent years, a series of metals that were supported on POPÀ PPh 3 or other derivatives, have been reported, [3] including rhodium, [4] platinum, [5] cobalt, [6] iron, [7] molybdenum, [7] zinc [8] and gold. [3] It was observed that introducing PPh 3 could create high density of ligand sites in the POPs, which led to increased loading stability and capability of the active metals and enhanced capability of catalyst recovery.…”