The latest versions of the Ross-Li model include kernels that represent isotropic reflection of the surface, describe backward reflection of soil and vegetation systems, characterize strong forward reflection of snow, and adequately consider the hotspot effect (i.e., RossThick-LiSparseReciprocalChen-Snow, RTLSRCS), theoretically able to effectively characterize BRDF/Albedo/NBAR features for various land surface types. However, a systematic evaluation of the RTLSRCS model is still lacking for various land cover types. In this paper, we conducted a thorough assessment of the RTLSRCS and RossThick-LiSparseReciprocalChen (RTLSRC) models in characterizing BRDF/Albedo/NBAR characteristics by using the global POLDER BRDF database. The primary highlights of this paper include the following: (1) Both models demonstrate high accuracy in characterizing the BRDF characteristics across 16 IGBP types. However, the accuracy of the RTLSRC model is notably reduced for land cover types with high reflectance and strong forward reflection characteristics, such as Snow and Ice (SI), Deciduous Needleleaf Forests (DNF), and Barren or Sparsely Vegetated (BSV). In contrast, the RTLSRCS model shows a significant improvement in accuracy for these land cover types. (2) These two models exhibit highly consistent albedo inversion across various land cover types (R2 > 0.9), particularly in black-sky and blue-sky albedo, except for SI. However, significant differences in white-sky albedo inversion persist between these two models for Evergreen Needleleaf Forests (ENF), Evergreen Broadleaf Forests (EBF), Urban Areas (UA), and SI (p < 0.05). (3) The NBAR values inverted by these two models are nearly identical across the other 15 land cover types. However, the consistency of NBAR results is relatively poor for SI. The RTLSRC model tends to overestimate compared to the RTLSRCS model, with a noticeable bias of approximately 0.024. This study holds significant importance for understanding different versions of Ross-Li models and improving the accuracy of satellite BRDF/Albedo/NBAR products.