The motion behaviors, rheological properties, and mechanical
properties
of a wax crystal mesoscale force chain network of waxy crude oil during
gelation were experimentally studied and simulated by rheo-optic in
situ measurement and computational fluid dynamics–discrete
element method (CFD–DEM) numerical simulation, respectively.
The motion behavior characteristics of wax crystals and the changes
in the average coordination number of wax crystal networks were obtained
at different temperatures. The study investigates the rule of crude
oil rheological deterioration, the increase of wax crystals, and the
changes in wax crystal motion behaviors with decreasing temperature.
The relationship between the structure of the mesoscale force chain
of the wax crystal network and the motion behaviors of the wax crystal
and its rheological properties was analyzed. The results show that
the average motion velocity of wax crystals or aggregates decreases
from 28.48 to 22.56 μm/s when the temperature decreases from
wax appearance temperature (48 °C) to 25 °C. The rotation
and rolling trend of wax crystals gradually flatten, and the average
coordination number increases 4.39 times. The viscosity of waxy crude
oil increases from 6.27 to 8369.7 mPa·s, and the average coordination
number of wax crystals obtained by CFD–DEM also increases significantly,
which confirms the experimental results. We also found that when the
system tended to gelation, a complex and stable force chain network
was formed between the wax crystals, with a force chain coverage of
87.93% and a significant increase in the pressure drop in the flow
field, which is consistent with the variation pattern of the system
viscosity. The micro–meso-dynamic behavior analysis of waxy
crude oil combined with CFD–DEM coupling provides a new way
to explore the rheological properties of waxy crude oil and the microscopic
mechanism of its modification.