A Priori Selection of the Type of Ionic Liquid

Arlt, Wolfgang; Buchele, Alexander

doi:10.1002/9783527654789.ch9

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Gas-phase Silp Hydroformylation Kinetics2

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“…Screening of the broad library of potential ionic liquids with respect to optimized solubility will help to further improve SILP systems in general. 1,37 ■ PROCESS DEVELOPMENTS IN SILP-CATALYZED HYDROFORMYLATION Recently, Rh-SILP catalysts have been reported that promote isomerization and hydroformylation in a single step. 38 These catalysts are capable of in situ isomerization of internal alkenes prior to hydroformylation.…”

Section: ■ Gas-phase Silp Hydroformylation Kineticsmentioning

confidence: 99%

See 1 more Smart Citation

Fifteen Years of Supported Ionic Liquid Phase-Catalyzed Hydroformylation: Material and Process Developments

Marinkovic

Riisager

Franke

et al. 2018

Ind. Eng. Chem. Res.

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This review describes the development of supported ionic liquid phase (SILP) materials as novel hydroformylation catalysts. Ligand-modified rhodium catalysts can be immobilized in a thin film of ionic liquid, which itself is dispersed on a porous material. The solid SILP catalysts have been improved with respect to activity, selectivity, and stability. In addition, their applicability in continuous gas-phase processes opens new opportunities for improved chemical production routes.

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Section: ■ Gas-phase Silp Hydroformylation Kineticsmentioning

confidence: 99%

“…This result indicates the importance of sufficient feedstock solubility in the ionic liquid film. Screening of the broad library of potential ionic liquids with respect to optimized solubility will help to further improve SILP systems in general. , …”

Section: Gas-phase Silp Hydroformylation Kineticsmentioning

confidence: 99%