We applied graphical methods and multivariate statistics to understand impacts of an unsewered slum catchment on nutrients and hydrochemistry of groundwater in Kampala, Uganda. Data were collected from 56 springs (groundwater), 22 surface water sites and 13 rain samples. Groundwater was acidic and dominated by Na, Cl and NO 3 . These ions were strongly correlated, indicating pollution originating from wastewater infiltration from on-site sanitation systems. Results also showed that rain, which was acidic, impacted on groundwater chemistry. Using Q-mode hierarchical cluster analysis, we identified three distinct water quality groups. The first group had springs dominated by Ca-Cl-NO 3 , low values of electrical conductivity (EC), pH and cations, and relatively high NO 3 values. These springs were shown to have originated from the acidic rains because their chemistry closely corresponded to ion concentrations that would occur from rainfall recharge, which was around 3.3 times concentrated by evaporation. The second group had springs dominated by Na-K-Cl-NO 3 and Ca-Cl-NO 3 , low pH but with higher values of EC, NO 3 and cations. We interpreted these as groundwater affected by both acid rain and infiltration of wastewater from urban areas. The third group had the highest EC values (average of 688 μS/cm), low pH and very high concentrations of NO 3 (average of 2.15 mmol/l) and cations. Since these springs were all located in slum areas, we interpreted them as groundwater affected by infiltration of wastewater from poorly sanitized slums areas. Surface water was slightly reducing and eutrophic because of wastewater effluents, but the contribution of groundwater to nutrients in surface water was minimal because o-PO 4 was absent, whereas NO 3 was lost by denitification. Our findings suggest that groundwater chemistry in the catchment is strongly influenced by anthropogenic inputs derived from nitrogen-containing rains and domestic wastewater.
Geology and hydrogeologyThe area, like many parts of SSA, is underlain by Precambrian basement rocks consisting of predominantly undifferentiated granite-gneiss rocks (silicate rocks) of the Buganda-Toro Cover Formation (Figure 2), which have been deeply weathered to lateritic regolith soils (about 30 m thick) (Key, 1992;Taylor and Howard, 1996;Taylor and Howard, 1999a). X-ray diffraction mineralogical analyses show that the weathered regolith is dominated by kaolinite and quartz minerals with minor amounts of 5861 IMPACTS OF UNSEWERED SLUM CATCHMENTS ON HYDROCHEMISTRY OF GROUNDWATER Figure 2. Context of the study area: (a) geology map, (b) land use map, (c) topographical map and (d) hydrogeologic cross section x-x illustrating groundwater flow and spring formation [adapted from (Miret-Gaspa, 2004)]