Severe plastic deformation (SPD) processes have attracted a great deal of both scientific and technological interest over the last few years as a consequence of the improvements that are possible to obtain in the microstructure and mechanical properties of the materials manufactured through the use of these kind of processes. However, the practical applications of such materials to obtain mechanical components are significantly fewer. As a direct consequence, the same thing has been observed in the development of studies that show the in-service behaviour of the mechanical components developed in this way. Since one of the industrial objectives of these SPD processes is to obtain functional parts, it is necessary to carry out studies to fill this gap. Therefore, in this study, an analysis of the wear that cams undergo when manufactured from an AA5083 aluminium-magnesium alloy is carried out. The cams were isothermally-forged from materials with and without previous SPD processing by equal channel angular pressing (ECAP). Subsequently, the wear behaviour of these cams was analysed by using specific equipment, which may have been considered to have a block-on-ring configuration, developed for testing in-service wear behaviour of mechanical parts. From this comparative wear study with cams, it is shown that previously-processed materials by ECAP have a better wear performance. Moreover, finite element modelling (FEM) simulations were also included to predict wear in the cams processed in this way. A good agreement between FEM and experimental results was obtained. It is this aspect of performing the wear tests on functional and real mechanical components, and not on laboratory samples, which makes this present research work novel.