PACS 78.47.+p, 78.55.HxThe form of time-resolved luminescence spectra has been studied for quartz annealed at 800 o C and pulsestimulated at 470 nm. Depending on the measurement temperature and the irradiation dose, the spectra may be de-convolved into two possible components to produce a principal and subsidiary lifetime component. Measurements between 20 and 200 o C show that both components are affected by thermal quenching of the associated luminescence, qualitatively so for the subsidiary one, but with an activation energy of 0.71 eV for the principal lifetime. Regarding influence of irradiation, time-resolved spectra consist of a single component below about 260 Gy but two components thereafter independent of irradiation. The irradiation-dependent features of the lifetimes are accounted for in terms of the relative importance of the various luminescence centers in quartz.1 Introduction Quartz is a common natural mineral with properties that make it amenable for application in radiation dosimetry using luminescence methods [1]. The luminescence properties of quartz including its sensitivity and luminescence lifetimes undergo notable changes when the quartz is annealed, and in particular, near its phase inversion temperatures of 573 and 867 o C [2, 3]. The physical processes leading up to the emission of luminescence in quartz may be investigated using time-resolved optical stimulation. The aim of this method is to separate in time the stimulation and emission of luminescence to enable measurement of time-resolved luminescence spectra which may be resolved into associated lifetimes, defined in this sense as the delay between stimulation and emission of luminescence [4,5]. A number of such studies show that annealing defines the detailed distribution of lifetimes with measurement temperature as well as the irradiation-dependent characteristics of the lifetimes [3,6]. In particular, it was noted [3] that spectra measured at certain temperatures could be accurately resolved into more than one component, a scenario that pointed to the possibility of involvement of multiple luminescence centers in the emission of luminescence from quartz.The aim of this work is to build on the findings described, specifically to study the influence of measurement temperature and irradiation on the principal and subsidiary luminescence lifetimes in natural quartz.