2008
DOI: 10.1016/j.orggeochem.2008.02.011
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A pyrolytic study of the speciation and isotopic composition of nitrogen in carboniferous shales of the North German Basin

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Cited by 20 publications
(3 citation statements)
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“…Indeed, early pyrolytic studies have shown that thermal degradation of nitrogen species in sedimentary rocks plays an important role in N2 accumulation in natural gas reservoirs; specifically, it was found that N2 is mainly generated at the final stage of gas generation after methane generation is practically exhausted Littke et al, 1995;Heim et al, 2012;Jurisch et al, 2012). Importantly, the inorganic, clay-bound nitrogen is liberated prior to organic nitrogen and converted to N2 due to its lower thermal stability during thermal degradation (Jurisch and Krooss, 2008;Jurisch et al, 2012).…”
Section: Metamorphic N2 Flux From Rocks To Gas Reservoir and Surface ...mentioning
confidence: 99%
“…Indeed, early pyrolytic studies have shown that thermal degradation of nitrogen species in sedimentary rocks plays an important role in N2 accumulation in natural gas reservoirs; specifically, it was found that N2 is mainly generated at the final stage of gas generation after methane generation is practically exhausted Littke et al, 1995;Heim et al, 2012;Jurisch et al, 2012). Importantly, the inorganic, clay-bound nitrogen is liberated prior to organic nitrogen and converted to N2 due to its lower thermal stability during thermal degradation (Jurisch and Krooss, 2008;Jurisch et al, 2012).…”
Section: Metamorphic N2 Flux From Rocks To Gas Reservoir and Surface ...mentioning
confidence: 99%
“…These gases have been sourced by the kerogen and the ammonium-bearing minerals in the re-heated source rocks of the Mesozoic basement. It is likely that the gases remaining in those source rocks are also rich in nitrogen (Krooss et al, 2005(Krooss et al, , 2006Jurisch et al, 2007;Jurisch and Krooss, 2008).…”
Section: Lower Jurassic Units Of the Mecsek Unitmentioning
confidence: 99%
“…Therefore, it is most likely that the nitrogen in the two gas fields is thermogenic. Usually, with the increase of the maturity, the δ 15 N values would turn to be heavier (Zhu et al, 2000;Jurisch and Krooss, 2008). As mentioned above, the thermogenic nitrogen generated at mature stage usually has the δ 15 N values of -10‰ ~ -1‰ (Zhu et al, 1998;Chen et al, 2003).…”
mentioning
confidence: 99%