A radiochemical study of isomerization of dimethylgermylium ion, with the reaction of Me2HGe+ cation with methyl tert-butyl ether as example

Myalochkin, D. L.; Кочина, Т. А.; Vrazhnov, D. V.; Аврорин, В. В.; Sinotova, E. N.

doi:10.1134/s1066362210010224

Search citation statements

Order By: Relevance

Paper Sections

Select...

Rearrangements Of Silylium Ions1

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2011

2020

Publication Types

Select...

Article3

Relationship

Self Cite0

Independent3

Authors

Journals

Cited by 3 publications

(1 citation statement)

References 5 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The interaction of Me 2 GeT þ cation with methyl-tert-butyl ether leads to the formation of dimethylmethoxygermanium (76%), that is the product of the germylation of ether, as well as of methane (9%) and methanol (15%) [92]. Now, it seems, that the higher interaction energy with ether (B3LYP/6-31G * estimate is 48 kcal/ mol) allows the part of cations to surpass a rather high barrier (60 kcal/mol) leading to the methane complex.…”

Section: Rearrangements Of Silylium Ionsmentioning

confidence: 99%