A review: Conversion of bioglycerol into 1,3-propanediol via biological and chemical method

Lee, C.S.; Aroua, Mohamed Kheireddine; Daud, Wan Mohd Ashri Wan; Cognet, Patrick; Peres-Lucchese, Yolande; Fabre, Paul-Louis; Reynes, Olivier; Latapie, Laure

doi:10.1016/j.rser.2014.10.033

Cited by 175 publications

(115 citation statements)

References 74 publications

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“…4 Although it is difficult to generate from biomass by chemical means, fermentative production of 1,3-PDO is relatively simple and environmentally friendly. 5 1,3-PDO is also a major product of glycerol fermentation employing many microbial species such as Clostridium, 6 Klebsiella, Citrobacter, 7 Lactobacillus, 8 and of genetically modified microorganisms. 9 The low crude glycerol price could lead to these feeds becoming the preferred substrates for microbial 1,3-PDO production.…”

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confidence: 99%

Combining bio- and chemo-catalysis for the conversion of bio-renewable alcohols: homogeneous iridium catalysed hydrogen transfer initiated dehydration of 1,3-propanediol to aldehydes

et al. 2016

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Abstract.Combining whole cell biocatalysis and chemocatalysis in a single reaction sequence avoids unnecessary separations, and the associated waste and energy consumption. Bacterial fermentation has been employed to convert waste glycerol from biodiesel production into 1,3-propanediol. This 1,3-propanediol can be extracted selectively from the aqueous fermentation broth using ionic liquids. 1,3-propanediol in ionic liquid solution was converted to propionaldehyde by hydrogen transfer initiated dehydration (HTID) catalysed by a Cp*IrCl 2 (NHC) (Cp* = pentamethylcyclopentadienyl; NHC = carbene ligand) complex. The use of an ionic liquid solvent enabled the reaction to be performed under reduced pressure, facilitating the isolation of the product, and improving the reaction selectivity. The Ir(III) catalyst in ionic liquid was found to be highly recyclable.Introduction.

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confidence: 99%

Combining bio- and chemo-catalysis for the conversion of bio-renewable alcohols: homogeneous iridium catalysed hydrogen transfer initiated dehydration of 1,3-propanediol to aldehydes

et al. 2016

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“…1,3‐Propanediol, which contains two hydroxyl groups in its structure is obtained directly from the fermentation of corn sugar. Not only it is used in cosmetic, food, pharmaceutical, and textile applications, but also as a precursor in the synthesis of polymers such as polyurethanes, polyether and polyesters or heterocyclic compounds . Both compounds are expected to be able to disrupt the crystalline structure of starch granules and reduce the inter and intramolecular starch‐starch interactions leading to the reduction of the glass transition temperature ( T g ).…”

Section: Introductionmentioning

confidence: 99%

D‐isosorbide and 1,3‐propanediol as plasticizers for starch‐based films: Characterization and aging study

González

Martin

González

et al. 2017

J of Applied Polymer Sci

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In the present work, D‐isosorbide and 1,3‐propanediol are proposed as alternative plasticizers obtained from renewable resources. Plasticized starch films were prepared by solvent casting method. The influence of using different “green” plasticizers in the final properties of starch‐based films was analyzed. Besides, the characterization of the films was also performed after storage time in order to evaluate the effect of the plasticizer on aging. UV‐spectrophotometry results showed better optical properties for both glycerol and D‐isosorbide films with higher transparency. The thermal and mechanical properties resulted influenced by the nature of the plasticizer. It was demonstrated that water vapor permeability was governed by the starch‐water interactions, whereas the oxygen permeability depended on the plasticizer's nature. The storage time affected the surface, mechanical, and thermal properties of the plasticized starch films. Atomic force microscopy results concluded that the topography of the films changed due to aging. The use of D‐isosorbide as plasticizer reduced the evolution of the mentioned properties and enhanced the reliability of the material. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 44793.

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“…Recently, the production of biodiesel has lead to the increased availability of crude glycerol (Lee et al . ; Tchakouteu et al . ).…”

Section: Introductionmentioning

confidence: 99%

Deletingpckimproves growth and suppresses by-product formation during 1,3-propanediol fermentation byKlebsiella pneumoniae

et al. 2017

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A review: Conversion of bioglycerol into 1,3-propanediol via biological and chemical method

Cited by 175 publications

References 74 publications

Combining bio- and chemo-catalysis for the conversion of bio-renewable alcohols: homogeneous iridium catalysed hydrogen transfer initiated dehydration of 1,3-propanediol to aldehydes

Combining bio- and chemo-catalysis for the conversion of bio-renewable alcohols: homogeneous iridium catalysed hydrogen transfer initiated dehydration of 1,3-propanediol to aldehydes

D‐isosorbide and 1,3‐propanediol as plasticizers for starch‐based films: Characterization and aging study

Deletingpckimproves growth and suppresses by-product formation during 1,3-propanediol fermentation byKlebsiella pneumoniae

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