h i g h l i g h t sA modular biocathode materials design was developed and optimized in BES. Dechlorination was improved using this composite metal and carbon-based material. SSB/GG/CB was optimum for dechlorination, followed by SSB/CB and SSB/GG. EIS analysis showed that the composite materials could improve the charge transfer. This modular design could be scalable with successive modules for BES scale-up.
t r a c tThis study developed and optimized a modular biocathode materials design in bioelectrochemical system (BES) using composite metal and carbon-based materials. The 4-chlorophenol (4-CP) dechlorination could be improved with such composite materials. Results showed that stainless steel basket (SSB) filled with graphite granules (GG) and carbon brush (CB) (SSB/GG/CB) was optimum for dechlorination, followed by SSB/CB and SSB/GG, with rate constant k of 0.0418 ± 0.0002, 0.0374 ± 0.0004, and 0.0239 ± 0.0002 h À1 , respectively. Electrochemical impedance spectroscopy (EIS) demonstrated that the composite materials with metal can benefit the electron transfer and decrease the charge transfer resistance to be 80.4 X in BES-SSB/GG/CB, much lower than that in BES-SSB (1674.3 X), BES-GG (387.3 X), and BES-CB (193.8 X). This modular cathode design would be scalable with successive modules for BES scaleup, and may offer useful information to guide the selection and design of BES materials towards dechlorination improvement in wastewater treatment.