number of independent energy sources are required to operate tens of billions of low-power electronic devices used for indoor applications. [3,4] Currently, most of the IoT-based devices installed in homes, offices, and workspaces are powered by disposable or rechargeable batteries. [5] However, the use of batteries to operate IoT-based devices presents significant technical challenges that have a decisive impact on the IoT sustainability. All batteries inherently have a limited lifespan. The electrical capacity of batteries rapidly decreases with aging and continuous charging and discharging. Thus, batteries should be continuously replaced and maintained, which increases the maintenance costs and creates environmental issues. [5,6] Therefore, semi-permanent power sources with small maintenance cost and few environmental constraints are required for sustainable IoT sensors. [7] Photovoltaics (PVs) are the most promising renewable-energy harvesting source. [8,9] Notably, organic PVs (OPVs) have a great potential to provide a self-sustaining power source for sensors under low-intensity illumination. Compared to other PV technologies (e.g., perovskite, dye-sensitized, and silicon solar cells), OPVs are a suitable power source for operating a variety of indoor applications due to the non-toxicity, tunability of the bandgap, and absorption spectrum of their materials. [10] OPVs can absorb energy within the visible-light range of 400-750 nm, which matches the emission spectrum of indoor light sources, e.g., light-emitting diodes (LED) and fluorescent lamps. [10,11] Stateof-the-art, the power conversion efficiency (PCE) of OPVs has been reported to approach 30% under diverse indoor conditions (250-1650 lux). [11,12] However, some aspects should be considered to enable the use of OPVs as an energy source for indoor-sensor applications.First, indoor OPVs should be able to sufficiently withstand light and thermal stress during long-term operation of sensor devices. OPVs suffer from stability issues caused by intensive light soaking and thermal cycling. [13] In particular, thermal stress causes severe morphological changes in the photoactive layer, which can degrade the performance of OPVs. We previously developed OPVs that have excellent thermal stability by optimizing the morphology of the active layer. [12] Moreover, the OPV needs to provide a suitable and stable direct-current (DC) voltage to operate the sensor devices. The open-circuit voltage (V OC ) generated by an indoor PV is less than 1 V, which Energy harvesting systems are attracting significant attention as a new power-supply technology to overcome the limitations of internet of things (IoT) devices usually established in an indoor environment such as power consumption, size, and usage time. Organic photovoltaics (OPVs) with high absorption coefficients at indoor light wavelengths are a promising energy source for the IoT-based sensors. However, OPVs in sensor platforms are not well addressed because of their insufficient and inconsistent power supply under ind...